3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Titanium catalysis for the synthesis of fine chemicals–development and trends

M Manßen, LL Schafer - Chemical Society Reviews, 2020 - pubs.rsc.org
Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Catalytic enantioselective construction of spiro quaternary carbon stereocenters

PW Xu, JS Yu, C Chen, ZY Cao, F Zhou, J Zhou - ACS Catalysis, 2019 - ACS Publications
The catalytic enantioselective assembly of spirocyclic molecules featuring a spiro quaternary
carbon stereocenter is currently of great interest because such privileged 3D structures are …

Transition-metal-catalyzed reactions in heterocyclic synthesis

I Nakamura, Y Yamamoto - Chemical reviews, 2004 - ACS Publications
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Construction of pyridine rings by metal-mediated [2+ 2+ 2] cycloaddition

JA Varela, C Saá - Chemical reviews, 2003 - ACS Publications
Pyridines are increasingly being manufactured synthetically rather than isolated from coal
tar. 1 It is desirable for syntheses to be simple, selective, flexible, and waste-free. Prominent …

[图书][B] Chemical reactivity theory: a density functional view

PK Chattaraj - 2009 - taylorfrancis.com
In the 1970s, Density Functional Theory (DFT) was borrowed from physics and adapted to
chemistry by a handful of visionaries. Now chemical DFT is a diverse and rapidly growing …

The chemistry of cyclopropanols

OG Kulinkovich - Chemical reviews, 2003 - ACS Publications
Cyclopropanol and its derivatives are carbocyclic homologues of enols, and there is an
obvious similarity in chemical properties between these classes of compounds due to the …

Design and synthesis of phosphole-based π systems for novel organic materials

Y Matano, H Imahori - Organic & biomolecular chemistry, 2009 - pubs.rsc.org
Phospholes are known to exhibit characteristic optical and electrochemical properties
derived from the phosphorus-bridged 1, 3-dienic π system. Particular interest has recently …

In the arena of enantioselective synthesis, titanium complexes wear the laurel wreath

DJ Ramon, M Yus - Chemical reviews, 2006 - ACS Publications
Asymmetry is ubiquitous in every part of Nature1 and has a great impact in many fields, not
only in chemistry but also even in arts. In the pharmaceutical area, asymmetry plays an …

1, 4-Bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadienes as strong salt-free reductants for generating low-valent early transition metals with electron-donating ligands

T Saito, H Nishiyama, H Tanahashi… - Journal of the …, 2014 - ACS Publications
Electron-rich organosilicon compounds, such as 1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-
cyclohexadiene (2a), 2, 5-dimethyl-1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadiene …