Bioinspired polymer systems with stimuli-responsive mechanical properties

L Montero de Espinosa, W Meesorn, D Moatsou… - Chemical …, 2017 - ACS Publications
Materials with switchable mechanical properties are widespread in living organisms and
endow many species with traits that are essential for their survival. Many of the mechanically …

Progress in bio-inspired sacrificial bonds in artificial polymeric materials

X Zhou, B Guo, L Zhang, GH Hu - Chemical Society Reviews, 2017 - pubs.rsc.org
Mimicking natural structures has been highly pursued in the fabrication of synthetic
polymeric materials due to its potential in breaking the bottlenecks in mechanical properties …

Mechanically robust, self-healable, and reprocessable elastomers enabled by dynamic dual cross-links

Y Chen, Z Tang, Y Liu, S Wu, B Guo - Macromolecules, 2019 - ACS Publications
Covalent cross-linking of rubbers is essential for obtaining high resilience and
environmental resistance but prevents healing and recycling. Integrating dynamic covalent …

Bioinspired engineering of sacrificial metal–ligand bonds into elastomers with supramechanical performance and adaptive recovery

Z Tang, J Huang, B Guo, L Zhang, F Liu - Macromolecules, 2016 - ACS Publications
Reinforcing rubbers and expanding their application galleries are two important issues in
material science and engineering. In this work, we demonstrate a bioinspired design of high …

Boronic acid esters and anhydrates as dynamic cross-links in vitrimers

M Gosecki, M Gosecka - Polymers, 2022 - mdpi.com
Growing environmental awareness imposes on polymer scientists the development of novel
materials that show a longer lifetime and that can be easily recycled. These challenges were …

Versatile applications of metallopolymers

S Goetz, S Zechel, MD Hager, GR Newkome… - Progress in Polymer …, 2021 - Elsevier
The incorporation of metal complexes into polymers leads to functional materials; whereas,
the properties of polymers–easy processability, light weight or the adjustable molar mass …

Role of sacrificial protein–metal bond exchange in mussel byssal thread self-healing

CNZ Schmitt, Y Politi, A Reinecke… - …, 2015 - ACS Publications
Marine mussels tether to seashore surfaces with byssal threads, proteinaceous fibers that
effectively dissipate energy from crashing waves. Protein–metal coordination bonds have …

Toughening elastomers using a mussel-inspired multiphase design

X Zhang, J Liu, Z Zhang, S Wu, Z Tang… - … applied materials & …, 2018 - ACS Publications
It is a challenge to simultaneously achieve high stretchability, high modulus, and
recoverability of polymers. Inspired by the multiphase structure of mussel byssus cuticles, we …

Carbon nanodots as high-functionality cross-linkers for bioinspired engineering of multiple sacrificial units toward strong yet tough elastomers

S Wu, M Qiu, Z Tang, J Liu, B Guo - Macromolecules, 2017 - ACS Publications
It is still a huge challenge to implement multiple energy dissipation mechanisms into
polymers toward strong yet tough elastomers. Here, we describe a biomimetic design for …

Mechanically robust, creep resistant and malleability retentive elastomer vitrimer enabled by integrating hydrogen bonds and boronic easters

L Wang, Y Liu, Y Wei, W Zeng, Z Cui, A Du - European Polymer Journal, 2023 - Elsevier
Vitrimer, featured with many fascinating properties, is a novel class of polymer, since their
network topologies can be rearranged at elevated temperatures without the loss of …