Hot wire chemical vapor deposition chemistry in the gas phase and on the catalyst surface with organosilicon compounds

Y Shi - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Hot wire chemical vapor deposition (HWCVD), also referred to as catalytic CVD
(Cat-CVD), has been used to produce Si-containing thin films, nanomaterials, and functional …

Thermal decomposition mechanism of tetraethylsilane by flash pyrolysis vacuum ultraviolet photoionization mass spectrometry and DFT calculations: the competition …

K Shao, X Liu, J Zhang - The Journal of Physical Chemistry A, 2023 - ACS Publications
Thermal decomposition of tetraethylsilane was investigated at temperatures up to 1330 K
using flash pyrolysis vacuum ultraviolet photoionization mass spectrometry. Density …

Theoretical Study on the Ring-Opening of 1,3-Disilacyclobutane and H2 Elimination

I Badran, A Rauk, YJ Shi - The Journal of Physical Chemistry A, 2012 - ACS Publications
The kinetics and thermochemistry of the decomposition pathways for 1, 3-disilacyclobutane
(1, 3-DSCB) in the gas phase were studied using the second-order Møller–Plesset (MP2) …

Competition of silene/silylene chemistry with free radical chain reactions using 1-methylsilacyclobutane in the hot-wire chemical vapor deposition process

I Badran, TD Forster, R Roesler… - The Journal of Physical …, 2012 - ACS Publications
The gas-phase reaction chemistry of using 1-methylsilacyclobutane (MSCB) in the hot-wire
chemical vapor deposition (CVD) process has been investigated by studying the …

Formation of methyl radicals from decomposition of methyl-substituted silanes over tungsten and tantalum filament surfaces

R Toukabri, N Alkadhi, YJ Shi - The Journal of Physical Chemistry …, 2013 - ACS Publications
The formation of methyl radical from the decomposition of four methyl-substituted silane
molecules, including monomethylsilane (MMS), dimethylsilane (DMS), trimethylsilane …

Effect of Si–H bond on the gas-phase chemistry of trimethylsilane in the hot wire chemical vapor deposition process

YJ Shi, XM Li, R Toukabri, L Tong - The Journal of Physical …, 2011 - ACS Publications
The effect of the Si–H bond on the gas-phase reaction chemistry of trimethylsilane in the hot-
wire chemical vapor deposition (HWCVD) process has been studied by examining its …

Growth of crystalline tungsten carbides using 1, 1, 3, 3-tetramethyl-1, 3-disilacyclobutane on a heated tungsten filament

Y Shi, I Badran, A Tkalych, WH Kan… - The Journal of …, 2013 - ACS Publications
A method of forming crystalline tungsten carbides was reported by exposing the heated
tungsten filament to 1, 1, 3, 3-tetramethyl-1, 3-disilacyclobutane (TMDSCB) in a hot-wire …

Carburization of tungsten filaments in a hot-wire chemical vapor deposition process using 1, 1, 3, 3-Tetramethyl-1, 3-disilacyclobutane

L Tong, YJ Shi - ACS Applied Materials & Interfaces, 2009 - ACS Publications
The alloying of tungsten filament when using 1, 1, 3, 3-tetramethyl-1, 3-disilacyclobutane
(TMDSCB) in a hot-wire chemical vapor deposition reactor was systematically studied by …

Promotion of exocyclic bond cleavages in the decomposition of 1, 3-disilacyclobutane in the presence of a metal filament

I Badran, YJ Shi - The Journal of Physical Chemistry A, 2015 - ACS Publications
The primary decomposition of 1, 3-disilacyclobutane (DSCB) on a tungsten filament and its
secondary gas-phase reactions in a hot-wire chemical vapor deposition (CVD) reactor have …

[PDF][PDF] Catalytic Decomposition of H2O (D2O) on a Heated Ir Filament to Produce O and OH (OD) Radicals

H Umemoto, H Kusanagi - Open Chemical Physics Journal, 2009 - shizuoka.repo.nii.ac.jp
Production of O atoms, H (D) atoms, and OH (OD) radicals was confirmed in the catalytic
decomposition of H2O (D2O) on a heated Ir filament by laser spectroscopic techniques, such …