Synthesis, coordination behavior, and catalytic properties of dppf congeners with an inserted carbonyl moiety

P Vosáhlo, I Císařová, P Štěpnička - New Journal of Chemistry, 2022 - pubs.rsc.org
Ferrocene phosphines have been extensively studied as ligands for coordination chemistry
and catalysis. Among the vast number of compounds reported to date, 1, 1′-bis …

Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents

A Padunnappattu, C Duhayon, V César… - Organometallics, 2022 - ACS Publications
Thanks to the onio-substitution strategy, tricationic imidazolium salt (1· H)(OTf) 3 featuring
two N-cyclopropenio substituents was readily prepared in a two-step procedure from 1 H …

Rational Design of Fe2(μ‐PR2)2(L)6 Coordination Compounds Featuring Tailored Potential Inversion

F Arrigoni, F Rizza, J Vertemara, R Breglia… - …, 2020 - Wiley Online Library
It was recently discovered that some redox proteins can thermodynamically and spatially
split two incoming electrons towards different pathways, resulting in the one‐electron …

Filling a Niche in “Ligand Space” with Bulky, Electron‐Poor Phosphorus (III) Alkoxides

S Hussein, D Priester, P Beet, J Cottom… - … A European Journal, 2019 - Wiley Online Library
The chemistry of phosphorus (III) ligands, which are of key importance in coordination
chemistry, organometallic chemistry and catalysis, is dominated by relatively electron‐rich …

Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines

L Hu, D Mahaut, N Tumanov, J Wouters, L Collard… - Dalton …, 2021 - pubs.rsc.org
ortho-Substituted and unsymmetrical 9-phospha-triptycenes were synthesized via two
synthetic approaches involving densely functionalized ortho-halogenated triarylmethane or …

Electronic Properties of a Cationic Triphenylphosphine Ligand Decorated with a (η5-C5H5)Fe Group in Late-Transition-Metal Complexes

C Malchau, F Loose, Y Mees, J Duppe, Y Sun… - …, 2020 - ACS Publications
The synthesis and characterization of a series of novel cationic multimetallic transition-metal
complexes based on the cationic phosphine ligand (η6-diphenylphosphinobenzene)(η5 …

Trizaine-based dehydrative condensation reagents bearing carbon-substituents

M Kitamura, S Komine, K Yamada, M Kunishima - Tetrahedron, 2020 - Elsevier
Herein, we report on the synthesis of alkyl-, aryl-, and alkynyl-substituted chlorotriazines and
their ammonium salts, and demonstrate their utility in dehydrative condensation reactions …

Tertiary phosphines: preparation and reactivity

EI Musina, AV Shamsieva, AS Balueva, AA Karasik - 2020 - books.rsc.org
This chapter covers the literature published during 2018 relating to the synthesis and the
reactivity of tertiary phosphines excluding the chemistry of their metal complexes. Although it …

Ferrocenové acylfosfiny

P Vosáhlo - 2023 - dspace.cuni.cz
Předložená disertační práce popisuje přípravu dvou typů doposud opomíjených acylfosfinů
s ferrocenovým skeletem, FcC (O) PR2 a R1 2PfcC (O) PR2 2 (Fc= ferrocenyl, fc= 1, 1' …

Quinquevalent phosphorus acids

P Bałczewski, K Owsianik - 2024 - books.rsc.org
This chapter covers scientific contributions in quinquevalent organo-phosphorus chemistry
published in the literature in 2021. The review is not comprehensive but shows the most …