Sub‐Stoichiometric Covalent Organic Frameworks

C Qian, X Li, WL Teo, Q Gao… - Advanced Functional …, 2024 - Wiley Online Library
Covalent organic frameworks (COFs) have garnered significant attention for nearly two
decades due to their exceptional structural designs, tunable properties, and wide‐ranging …

New Advances in Covalent Network Polymers via Dynamic Covalent Chemistry

Z Lei, H Chen, S Huang, LJ Wayment, Q Xu… - Chemical …, 2024 - ACS Publications
Covalent network polymers, as materials composed of atoms interconnected by covalent
bonds in a continuous network, are known for their thermal and chemical stability. Over the …

Controlling the Degree of Interpenetration in Chiral Three-Dimensional Covalent Organic Frameworks via Steric Tuning

K Wang, B Hou, J Dong, H Niu, Y Liu… - Journal of the American …, 2024 - ACS Publications
Network interpenetration plays a crucial role in functionalizing porous framework materials.
However, controlling the degree of interpenetration in covalent organic frameworks (COFs) …

Construction of Benzoxazine‐linked One‐dimensional Covalent Organic Frameworks Using the Mannich Reaction

C Cheng, Y Liu, G Sheng, X Jiang… - Angewandte Chemie …, 2024 - Wiley Online Library
Covalent polymerization of organic molecules into crystalline one‐dimensional (1D)
polymers is effective for achieving desired thermal, optical, and electrical properties, yet it …

Highly Crystalline Helical Covalent Organic Frameworks

J Sun, L Peng, Y Liu, D Wei - Chemistry of Materials, 2024 - ACS Publications
Controllable synthesis of highly crystalline covalent organic frameworks (COFs) with unique
structures is important for fundamental research and their practical applications. Herein, we …

Unprecedented Planar-Square SiO4-Moiety Connected Two-Dimensional Covalent Organic Frameworks for Anodic Potassium Ion Storage

Z Liu, W Liu, Y Chen, X Yang, Y Liu, Y Jin… - CCS …, 2024 - chinesechemsoc.org
Developing new linkages by means of new reversible bonds is essential towards expanding
the scope of covalent organic frameworks (COFs), which has become one of the major …

Ionic Covalent Organic Frameworks Consisting of Tetraborate Nodes and Flexible Linkers

LJ Wayment, S Huang, H Chen, Z Lei, A Ley… - Angewandte …, 2024 - Wiley Online Library
Covalent organic frameworks (COFs) have emerged as versatile materials with many
applications, such as carbon capture, molecular separation, catalysis, and energy storage …

Dynamic Entwined Topology in Helical Covalent Polymers Dictated by Competing Supramolecular Interactions

LJ Wayment, SJ Teat, S Huang… - Angewandte Chemie …, 2024 - Wiley Online Library
Naturally occurring polymeric structures often consist of 1D polymer chains intricately folded
and entwined through non‐covalent bonds, adopting precise topologies crucial for their …

Construction of single-crystal 3D covalent organic framework with three crossing sets of 2D sheets entanglement

B Yu, S Geng, X Ding, X Zhou, Y Jin, H Wang, X Wang… - Chem, 2024 - cell.com
It still remains a challenge to build 3D covalent organic frameworks (COFs) with multiple
crossing sets of parallel layers through entanglement due to the complex interactions and …

“Homoleptic” Tetracoordinate Boron Compounds

X Li, Q Song - Inorganic Chemistry, 2024 - ACS Publications
“Homoleptic” tetracoordinate boron compounds, in which the central boron atom links to four
identical atoms, are a special and important family of boron compounds. During the past …