Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Gold-catalyzed reactions of specially activated alkynes, allenes, and alkenes

D Campeau, DF León Rayo, A Mansour… - Chemical …, 2020 - ACS Publications
This review describes the gold-catalyzed reactions of specially activated alkynes, allenes,
and alkenes. Such species are characterized by the presence of either electron-donating or …

Synergistic catalysis: a powerful synthetic strategy for new reaction development

AE Allen, DWC MacMillan - Chemical science, 2012 - pubs.rsc.org
Synergistic catalysis is a synthetic strategy wherein both the nucleophile and the
electrophile are simultaneously activated by two separate and distinct catalysts to afford a …

Reactivity of gold complexes towards elementary organometallic reactions

M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

When organocatalysis meets transition‐metal catalysis

C Zhong, X Shi - European Journal of Organic Chemistry, 2010 - Wiley Online Library
In the past several years, applications of transition metal complexes in tuning the reactivity of
organocatalyst‐promoted transformations have attracted increasing attention in the synthetic …

Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C C Coupling and Other Reactions

MH Pérez‐Temprano, JA Casares… - Chemistry–A European …, 2012 - Wiley Online Library
Bimetallic catalysis refers to homogeneous processes in which either two transition metals
(TM), or one TM and one Group 11 (G11) element (occasionally Hg also), cooperate in a …

Gold‐Catalyzed Cross‐Couplings: New Opportunities for C C Bond Formation

P Garcia, M Malacria, C Aubert, V Gandon… - …, 2010 - Wiley Online Library
Cross‐coupling is a powerful tool for the rapid construction of highly valuable compounds. In
this area of chemical transformations, new catalysts have recently emerged. Combining both …

Catalyzed catalysis using carbophilic Lewis acidic gold and Lewis basic palladium: synthesis of substituted butenolides and isocoumarins

Y Shi, KE Roth, SD Ramgren… - Journal of the American …, 2009 - ACS Publications
A new strategy for gold and palladium dual-catalytic reactivity and turnover, called catalyzed
catalysis, enhanced the synthetic usefulness of vinylgold intermediates by providing dual …

Organogold reactivity with palladium, nickel, and rhodium: transmetalation, cross-coupling, and dual catalysis

JJ Hirner, Y Shi, SA Blum - Accounts of chemical research, 2011 - ACS Publications
Using two transition metals to simultaneously catalyze a reaction can offer distinct
opportunities for reactivity and selectivity when compared to using single-metal catalyst …

Alkyne difunctionalization by dual gold/photoredox catalysis

A Tlahuext‐Aca, MN Hopkinson… - … A European Journal, 2016 - Wiley Online Library
Highly selective tandem nucleophilic addition/cross‐coupling reactions of alkynes have
been developed using visible‐light‐promoted dual gold/photoredox catalysis. The …