Exciton transport in molecular aggregates–from natural antennas to synthetic chromophore systems

T Brixner, R Hildner, J Köhler… - Advanced Energy …, 2017 - Wiley Online Library
The transport of excitation energy in molecular aggregates is of crucial importance for the
function of organic optoelectronic devices and next‐generation solar cells. First, this review …

Single-molecule fluorescence spectroscopy of photosynthetic systems

T Kondo, WJ Chen, GS Schlau-Cohen - Chemical reviews, 2017 - ACS Publications
Photosynthesis begins when a network of pigment–protein complexes captures solar energy
and transports it to the reaction center, where charge separation occurs. When necessary …

Strong coupling between chlorosomes of photosynthetic bacteria and a confined optical cavity mode

DM Coles, Y Yang, Y Wang, RT Grant… - Nature …, 2014 - nature.com
Strong exciton–photon coupling is the result of a reversible exchange of energy between an
excited state and a confined optical field. This results in the formation of polariton states that …

Robust excitons inhabit soft supramolecular nanotubes

DM Eisele, DH Arias, X Fu… - Proceedings of the …, 2014 - National Acad Sciences
Nature's highly efficient light-harvesting antennae, such as those found in green sulfur
bacteria, consist of supramolecular building blocks that self-assemble into a hierarchy of …

Two-dimensional electronic spectroscopy reveals ultrafast energy diffusion in chlorosomes

J Dostal, T Mancal, R Augulis, F Vacha… - Journal of the …, 2012 - ACS Publications
Chlorosomes are light-harvesting antennae that enable exceptionally efficient light energy
capture and excitation transfer. They are found in certain photosynthetic bacteria, some of …

Ultrafast anisotropy decay reveals structure and energy transfer in supramolecular aggregates

V Erić, JL Castro, X Li, L Dsouza… - The Journal of …, 2023 - ACS Publications
Chlorosomes from green bacteria perform the most efficient light capture and energy
transfer, as observed among natural light-harvesting antennae. Hence, their unique …

Manifestation of hydrogen bonding and exciton delocalization on the absorption and two-dimensional electronic spectra of chlorosomes

V Eric, X Li, L Dsouza, SK Frehan… - The Journal of …, 2023 - ACS Publications
Chlorosomes are supramolecular aggregates that contain thousands of bacteriochlorophyll
molecules. They perform the most efficient ultrafast excitation energy transfer of all natural …

Structure of light-harvesting aggregates in individual chlorosomes

LM Günther, M Jendrny, EA Bloemsma… - The Journal of …, 2016 - ACS Publications
Among all photosynthetic organisms, green bacteria have evolved one of the most efficient
light-harvesting antenna, the chlorosome, that contains hundreds of thousands of …

Anisotropic Dissymmetry Factor, g: Theoretical Investigation on Single Molecule Chiroptical Spectroscopy

M Wakabayashi, S Yokojima… - The Journal of …, 2014 - ACS Publications
A formula for an anisotropic dissymmetry factor g evaluating the chiroptical response of
orientationally fixed molecules is derived. Incorporating zeroth-and first-order multipole …

Fluorescence anisotropy reloaded—emerging polarization microscopy methods for assessing chromophores' organization and excitation energy transfer in single …

R Camacho, D Täuber, IG Scheblykin - Advanced Materials, 2019 - Wiley Online Library
Fluorescence polarization is widely used to assess the orientation/rotation of molecules, and
the excitation energy transfer between closely located chromophores. Emerging since the …