Ring‐opening metathesis polymerization (ROMP) has become one of the most important
living polymerizations. Cyclopropenes (CPEs) remain underexplored for ROMP. Described …

The mechanism of ring-opening metathesis polymerization (ROMP) for a set of
functionalized norbornenyl monomers initiated by a Grubbs third generation precatalyst …

Ambient temperature ring-opening metathesis polymerization (ROMP) of unhindered
cycloolefins is crucial for industrial applications from a sustainable perspective. However …

An unsaturated polymer's cis/trans-olefin content has a significant influence on its properties.
For polymers obtained by ring-opening metathesis polymerization (ROMP), the cis/trans …

Abstract Development of versatile ruthenium olefin-metathesis catalysts with high activity,
stability, and selectivity is a continuous challenge. Here we report highly controllable …

For decades, cyclopolymerization of α, ω-diyne derivatives has been an effective method to
synthesize various soluble polyacetylenes containing five-to seven-membered rings in the …

Cyclopolymerization is a powerful method for synthesizing polyacetylenes containing four‐to
seven‐membered rings. However, the structure of the repeat unit only consists of mono …

The creation of polymers without metal contamination remains a significant challenge for
metathesis-based polymerization techniques and has complicated applications in …

Poly (δ-pinene), PδP, is a promising new material derived from naturally abundant α-pinene.
One of the persistent by-products in the synthesis of δ-pinene is α-pinene which required …

Materials formed by the ring‐opening metathesis polymerization (ROMP) of cyclic olefins are
highly valued for industrial and academic applications but are difficult to prepare free of …