Recent Progress on the Functionalization of Endohedral Metallofullerenes
S Wang, X Zhang, X Tan, H Li, S Dai, B Yao, X Liu… - Inorganics, 2023 - mdpi.com
Functionalization of endohedral metallofullerenes (EMFs) plays an important role in
exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable …
exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable …
Chemistry of difluoromethylenefullerenes
VA Brotsman, NS Lukonina, AA Goryunkov - Russian Chemical Bulletin, 2023 - Springer
Difluoromethylenefullerenes belonging to structurally flexible bridged fullerene derivatives
have a rare distinctive feature, viz., insertion of CF2 group into the C= C bond of the fullerene …
have a rare distinctive feature, viz., insertion of CF2 group into the C= C bond of the fullerene …
Tuning Photoinduced Electron Transfer in POM‐Bodipy Hybrids by Controlling the Environment: Experiment and Theory
G Toupalas, J Karlsson, FA Black… - Angewandte Chemie …, 2021 - Wiley Online Library
The optical and electrochemical properties of a series of polyoxometalate (POM) oxoclusters
decorated with two bodipy (boron‐dipyrromethene) light‐harvesting units were examined …
decorated with two bodipy (boron‐dipyrromethene) light‐harvesting units were examined …
Reactivity of Open-Shell Metallofullerene Anions: Synthesis, Crystal Structures, and Electrochemical Properties of Benzylated Gd@C2v-C82
X Zhou, YR Yao, Y Hu, L Yang, S Yang, Y Zhang… - Inorganics, 2023 - mdpi.com
The reactivity of the open-shell Gd@ C 2v-C82 with different charge states towards benzyl
bromide was investigated.[Gd@ C 2v-C82] 3− exhibited enhanced activity relative to Gd@ C …
bromide was investigated.[Gd@ C 2v-C82] 3− exhibited enhanced activity relative to Gd@ C …
Decisive role of non-rare earth metals in high-regioselectivity addition of μ 3-carbido clusterfullerene
Endohedral clusterfullerenes featuring encapsulation of metal clusters which transfer
electrons to the outer fullerene cages show intriguing chemical properties different from …
electrons to the outer fullerene cages show intriguing chemical properties different from …
Molecular tailoring of donor and acceptor materials of organic solar cells for improvement of their optoelectronic properties
MA Ansari, A Hafeez, M Mustafa… - Materials Science in …, 2022 - Elsevier
Improvement in the efficiency of organic solar cell (OSC) is one of the hot topics of the
modern-day research. Despite environment friendliness and several other practical …
modern-day research. Despite environment friendliness and several other practical …
Anomalous Cis‐Conformation Regioselectivity of Heterocycle‐Fused Sc3N@D3h‐C78 Derivatives
Endohedral clusterfullerenes exhibit unique chemical properties due to intramolecular
electron transfer of the encaged metal cluster to the outer fullerene cages. We report the …
electron transfer of the encaged metal cluster to the outer fullerene cages. We report the …
Precision Chemistry of Metallofullerenes and Graphene: Recent Advances
Precision chemistry of synthetic carbon allotropes including fullerene and graphene,
characterized by a well‐controlled and spatially resolved addends bonding, has received …
characterized by a well‐controlled and spatially resolved addends bonding, has received …
Insights into the Diels–Alder Reaction of [M3N@Ih-C80]0/1+ (M = Sc or Y): Effects of Oxidation on the Reactivity and Regioselectivity
Y Xiong, M Li, H Zheng, J Dang, X Zhao - Organometallics, 2023 - ACS Publications
Diels–Alder (DA) cycloaddition is one important method to generate new derivatives of
fullerenes, which is important to accelerating their application. In this study, the DA reaction …
fullerenes, which is important to accelerating their application. In this study, the DA reaction …
Unexpected formation of 1, 2-and 1, 4-bismethoxyl Sc 3 N@ I hC 80 derivatives via regioselective anion addition: An unambiguous structural identification and …
An attempt to achieve heterocyclic cycloadducts of Sc3N@ Ih-C80via reaction with Ph2CO,
PhCCPh or PhCN in the presence of tetrabutylammonium hydroxide (TBAOH) stored in …
PhCCPh or PhCN in the presence of tetrabutylammonium hydroxide (TBAOH) stored in …