Experimental binding energies in supramolecular complexes

F Biedermann, HJ Schneider - Chemical reviews, 2016 - ACS Publications
On the basis of many literature measurements, a critical overview is given on essential
noncovalent interactions in synthetic supramolecular complexes, accompanied by analyses …

Binding mechanisms in supramolecular complexes

HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …

Deep inside cucurbiturils: physical properties and volumes of their inner cavity determine the hydrophobic driving force for host–guest complexation

WM Nau, M Florea, KI Assaf - Israel Journal of Chemistry, 2011 - Wiley Online Library
Abstract Cucurbit [n] urils (CBn) bind guest molecules through a combination of electrostatic
interactions with the carbonyl rims and hydrophobic interactions with the inner cavity …

The mathematical origins of the kinetic compensation effect: 1. The effect of random experimental errors

PJ Barrie - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
The kinetic compensation effect states that there is a linear relationship between Arrhenius
parameters ln A and E for a family of related processes. It is a widely observed phenomenon …

Solvent reorganization and thermodynamic enthalpy-entropy compensation

E Grunwald, C Steel - Journal of the American Chemical Society, 1995 - ACS Publications
This paper develops a formalism for treatingthe solvent reorganization that accompanies all
chemical reactions and physical processes in liquid solutions. In particular, cage …

Enthalpy–entropy compensation (EEC) effect: a revisit

A Pan, T Biswas, AK Rakshit… - The Journal of Physical …, 2015 - ACS Publications
A short account of the developments and perspectives of IKR (iso-kinetic relation) and EEC
(enthalpy (H)–entropy (S) compensation) has been presented. The IKR and EEC are known …

Catalytic asymmetric indolization by a desymmetrizing [3+ 2] annulation strategy

C Wu, Z Chang, C Peng, C Bai, J Xing, X Dou - Chemical Science, 2023 - pubs.rsc.org
A new catalytic asymmetric indolization reaction by a desymmetrizing [3+ 2] annulation
strategy is developed. The reaction proceeds via a rhodium-catalyzed enantioposition …

Chromotropism of coordination compounds and its applications in solution

W Linert, Y Fukuda, A Camard - Coordination Chemistry Reviews, 2001 - Elsevier
Chromotropic properties of coordination varying solvent, ionic species in solution,
temperature, pressure, magnetic field or light irradiation are reviewed. Structural varieties …

Recent advances in the description of the structure of water, the hydrophobic effect, and the like-dissolves-like rule

R Schmid - Monatshefte für Chemie/Chemical Monthly, 2001 - Springer
Following a critical survey of the vast recent literature, the state of the art may be
summarized as follows:(A) Water structure. The key is appreciating the next-nearest …

Bindungsmechanismen in supramolekularen Komplexen

HJ Schneider - Angewandte Chemie, 2009 - Wiley Online Library
Abstract Kräfte‐Sammelsurium: Supramolekulare Komplexe, wie der gezeigte, beruhen
meist auf einer Kombination unterschiedlichster Wechselwirkungen, wie Ionenpaarbildung …