Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …

Stable organic nitroxyl radicals are an important class of catalysts for oxidation reactions, but
their wide applications are hindered by their steric hinderance, high cost, complex operation …

Herein, we report a Ni-catalyzed C (sp2)–H hydroxylation of aryl bromides with N2O as an
oxygen-atom donor. The reaction is enabled by a 1, 4-Ni translocation that results in …

Herein we present the catalytic activation of N2O at a BiI⇄ BiIII redox platform. The activation
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …

The development of catalytic chemical processes that enable the revalorization of nitrous
oxide (N2O) is an attractive strategy to alleviate the environmental threat posed by its …

We describe an eco-friendly, practical and operationally simple procedure for the bis
(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic …

Herein, we report the efficient degradation of N2O with a well‐defined bis (silylene) amido
iron complex as catalyst. The deoxygenation of N2O using the iron silanone complex 4 as a …

One-pot oxidative transformation of alcohols into esters is very attractive, but metal-based
catalysts are used in the reported routes. We discovered that the basic ionic liquid 1-ethyl-3 …

The facile oxidation of alcohols to carboxylate salts and H2 is achieved using a simple and
readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an …

The acceptorless dehydrogenation of diverse aromatic and aliphatic primary alcohols to
corresponding carboxylic acids has been accomplished by self-supported NHC-Ru single …