MgCl2 supported Ziegler–Natta (Z–N) catalysts have emerged as the most exciting chemical
process for polyolefin technology, which is responsible for the production of∼ 150 million …

The polyolefins production has increased rapidly in the 40 years to make polyolefins the
major tonnage plastics material worldwide. In 2003, 55 million tons of polyethene and 38 …

Catalysis continues to play a vital role in polymerization of such olefins as ethylene and
propylene. Developments toward higher activity Ziegler-Natta catalysts have been based in …

A relatively compact, but nonetheless comprehensive, review of the most important
preparative methods for the synthesis and chemical modification of polymers. The contents …

Although Ziegler–Natta (ZN) catalysts play a major role in the polyolefin market, a true
understanding of their properties at the molecular level is still missing. In particular, there is a …

Although the formation of nanosized and defective δ-MgCl2 is essential for the performance
of Ziegler–Natta catalysts, the process has not sufficiently been elucidated due to certain …

Abstract MgCl 2 supported Ziegler-Natta catalysts for the polymerization of olefins have had
recently a spectacular success in simplyfling polymerization processes and improving …

In situ characterization and reaction studies of working catalytic systems are an issue of
current interest. We present studies on well characterized model systems, ie, deposited …

In this work a new model for the polymerization of olefins in a loop reactor is presented. The
reactor is modelled as two tubular reactors interconnected. In contrast to the traditional …

Heterogeneous Ziegler–Natta and Phillips-type olefin polymerization catalysts have the
monopoly of isotactic polypropylene production and a large share in the market of high …