Molecular clusters of π-systems: theoretical studies of structures, spectra, and origin of interaction energies

KS Kim, P Tarakeshwar, JY Lee - Chemical reviews, 2000 - ACS Publications
Much interest has been evinced on the properties of weakly bound van der Waals
complexes of π-systems because of their utility in diverse fields (Figure 1). 1-14 Theoretical …

Molecular aspects of halide ion hydration: The cluster approach

WH Robertson, MA Johnson - Annual review of physical …, 2003 - annualreviews.org
▪ Abstract This review provides a historical context for our understanding of the hydration
shell surrounding halide ions and illustrates how the cluster systems can be used, in …

The structure of microsolvated benzene derivatives and the role of aromatic substituents

B Brutschy - Chemical Reviews, 2000 - ACS Publications
Molecular clusters are nowadays preferred model systems to study both the energetics and
dynamics of molecules in a tailored molecular environment. 1-5 For the physical chemist …

Spectroscopy of metal ion complexes: gas-phase models for solvation

MA Duncan - Annual review of physical chemistry, 1997 - annualreviews.org
▪ Abstract Weakly bound metal ion complexes are produced in molecular beams and studied
with mass-selected laser photodissociation spectroscopy. The metal ions Mg+ and Ca+ are …

Infrared consequence spectroscopy of gaseous protonated and metal ion cationized complexes

TD Fridgen - Mass spectrometry reviews, 2009 - Wiley Online Library
In this article, the new and exciting techniques of infrared consequence spectroscopy
(sometimes called action spectroscopy) of gaseous ions are reviewed. These techniques …

Size selectivity by cation–π interactions: Solvation of and by benzene and water

OM Cabarcos, CJ Weinheimer, JM Lisy - The Journal of chemical …, 1999 - pubs.aip.org
Size-specific interaction of alkali metal ions with aromatic side chains has been proposed as
a mechanism for selectivity in some K+ channel proteins. Experiments on gas-phase cluster …

Vibrational Spectroscopy of the Cl-(H2O)n Anionic Clusters, n = 1−5

JH Choi, KT Kuwata, YB Cao… - The Journal of Physical …, 1998 - ACS Publications
The hydrogen-bonded and free OH stretch modes of Cl-(H2O) n (n= 1− 5) have been
observed by vibrational predissociation spectroscopy in the 2.6− 3.2 μm region. Besides …

Hydration Energies and Structures of Alkaline Earth Metal Ions, M2+(H2O)n, n = 5−7, M = Mg, Ca, Sr, and Ba

SE Rodriguez-Cruz, RA Jockusch… - Journal of the American …, 1999 - ACS Publications
The evaporation of water from hydrated alkaline earth metal ions, produced by electrospray
ionization, was studied in a Fourier transform mass spectrometer. Zero-pressure-limit …

Microscopic hydration of the fluoride anion

OM Cabarcos, CJ Weinheimer, JM Lisy… - The Journal of chemical …, 1999 - pubs.aip.org
A combined experimental and theoretical investigation of the step-wise hydration of the
fluoride ion has been performed in order to characterize the details of its solvation at the …

Infrared spectroscopy of hydrated amino acids in the gas phase: protonated and lithiated valine

A Kamariotis, OV Boyarkin, SR Mercier… - Journal of the …, 2006 - ACS Publications
We report here infrared spectra of protonated and lithiated valine with varying degrees of
hydration in the gas phase and interpret them with the help of DFT calculations at the …