Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Molecules with restricted rotation around a single bond or atropisomers are found in a wide
number of natural products and bioactive molecules as well as in chiral ligands for …

Atropisomers beyond the C–C axis (denoted as X–Y herein) are important addition to the
repertoire of axially chiral compounds, which have received much attention in recent years …

The first highly atroposelective construction of N− N axially chiral indole scaffolds was
established via a new strategy of de novo ring formation. This strategy makes use of the …

Atropisomeric C–N compounds belong to an important class of axially chiral compounds.
However, whereas the asymmetric synthesis of biaryl atropisomers have been well …

Comprehensive Summary A new strategy for the enantioselective synthesis of axially chiral
3, 3'‐bisindoles was devised by the direct coupling of two indole rings. This strategy makes …

Conspectus Atropisomerism is a type of axial chirality resulting from hindered rotation about
a σ bond that gives rise to nonsuperimposable stereoisomers (termed “atropisomers”). The …

We report a highly enantioselective radical-based hydroamination of enol esters with
sulfonamides jointly catalyzed by an Ir photocatalyst, Brønsted base, and tetrapeptide thiol …

The first catalytic asymmetric synthesis of N–N axially chiral compounds has been
accomplished via a quinidine catalyzed N-allylic alkylation reaction. These N–N axially …

Axially chiral indole‐based frameworks have been recognized as a class of important five‐
membered heterobiaryls and developing catalytic asymmetric approaches for constructing …