Enzymes immobilized in mesoporous silica: A physical–chemical perspective

N Carlsson, H Gustafsson, C Thörn, L Olsson… - Advances in colloid and …, 2014 - Elsevier
Mesoporous materials as support for immobilized enzymes have been explored extensively
during the last two decades, primarily not only for biocatalysis applications, but also for …

Small molecules, non-covalent interactions, and confinement

G Buntkowsky, M Vogel - Molecules, 2020 - mdpi.com
This review gives an overview of current trends in the investigation of small guest molecules,
confined in neat and functionalized mesoporous silica materials by a combination of solid …

1 H chemical shift anisotropy: a high sensitivity solid-state NMR dynamics probe for surface studies?

SA Southern, DJ Liu, P Chatterjee, Y Li… - Physical Chemistry …, 2023 - pubs.rsc.org
Dynamics play significant roles in chemistry and biochemistry—molecular motions impact
both large-and small-scale chemical reactions in addition to biochemical processes. In many …

Effect of Hydrogen Bonding to Water on the 31P Chemical Shift Tensor of Phenyl- and Trialkylphosphine Oxides and α-Amino Phosphonates

G Begimova, EY Tupikina, VK Yu… - The Journal of …, 2016 - ACS Publications
The effect of hydrogen bonding to water on the 31P NMR chemical shift tensor in the titled
compounds has been studied experimentally and simulated theoretically using the DFT …

Spatial arrangement of dynamic surface species from solid-state NMR and machine learning-accelerated MD simulations

T Kobayashi, DJ Liu, FA Perras - Chemical Communications, 2022 - pubs.rsc.org
The surface arrangement of motional organic functionalities is explored by experimental
dipolar coupling measurements and the prediction of motionally-averaged coupling constant …

Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica

G Buntkowsky, S Döller, N Haro-Mares… - Zeitschrift für …, 2022 - degruyter.com
This review gives an overview of current trends in the investigation of confined molecules
such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat …

Size matters: altering the metal-surface coordination in micropores via structural confinement effects

SA Southern, A Thompson, AD Sadow… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Solid-state NMR experiments were used to investigate the dynamics of supported
complexes grafted to a series of silica gel materials of varied pore sizes. Through dipolar …

Recent advances in solid state NMR of small molecules in confinement

M Werner, N Rothermel, H Breitzke… - Israel Journal of …, 2014 - Wiley Online Library
In the past years, porous media have become a major focus of materials science, due to
their versatile properties, such as high surface area, low specific weight, high surface …

Structural insights into peptides bound to the surface of silica nanopores

M Brodrecht, B Kumari… - … A European Journal, 2019 - Wiley Online Library
The structure and surface functionalization of biologically relevant silica‐based hybrid
materials was investigated by 2D solid‐state NMR techniques combined with dynamic …

Effect of Noncovalent Interactions on the 31P Chemical Shift Tensor of Phosphine Oxides, Phosphinic, Phosphonic, and Phosphoric Acids, and Their Complexes with …

IG Shenderovich - The Journal of Physical Chemistry C, 2013 - ACS Publications
The effect of noncovalent interactions such as C–H··· O and O–H··· O hydrogen bonds and
coordination to Pb2+ on the 31P NMR chemical shift tensor in the titled compounds has …