Ruthenium-nitrosyl complexes as NO-releasing molecules, potential anticancer drugs, and photoswitches based on linkage isomerism
I Stepanenko, M Zalibera, D Schaniel, J Telser… - Dalton …, 2022 - pubs.rsc.org
The synthesis of new types of mono-and polynuclear ruthenium nitrosyl complexes is driving
progress in the field of NO generation for a variety of applications. Light-induced Ru-NO …
progress in the field of NO generation for a variety of applications. Light-induced Ru-NO …
Metal complexes of corrole
S Nardis, F Mandoj, M Stefanelli, R Paolesse - Coordination Chemistry …, 2019 - Elsevier
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …
The story of 5d metallocorroles: from metal–ligand misfits to new building blocks for cancer phototherapeutics
Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
Seven clues to ligand noninnocence: the metallocorrole paradigm
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
X-ray absorption spectroscopy as a probe of ligand noninnocence in metallocorroles: the case of copper corroles
The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Rhenium Corrole Dimers: Electrochemical Insights into the Nature of the Metal–Metal Quadruple Bond
AB Alemayehu, LJ McCormick-McPherson… - Inorganic …, 2021 - ACS Publications
The interaction of free-base triarylcorroles with Re2 (CO) 10 in 1, 2-dichlorobenzene in the
presence of 2, 6-lutidine at 180° C under strict anerobic conditions afforded approximately …
presence of 2, 6-lutidine at 180° C under strict anerobic conditions afforded approximately …
Cobalt-and rhodium-corrole-triphenylphosphine complexes revisited: The question of a noninnocent corrole
A reinvestigation of cobalt–corrole–triphenylphosphine complexes has yielded an
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
Electronic structure of cobalt–corrole–pyridine complexes: noninnocent five-coordinate Co (II) corrole–radical states
Two sets of complexes of Co–triarylcorrole–bispyridine complexes, Co [T p XPC](py) 2 and
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …
A DMRG/CASPT2 investigation of metallocorroles: quantifying ligand noninnocence in archetypal 3d and 4d element derivatives
Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …
theory have been used to quantitatively compare the degree of ligand noninnocence …
Structure and reactivity of one-and two-electron oxidized manganese (V) nitrido complexes bearing a bulky corrole ligand
H Shi, R Liang, DL Phillips, HK Lee… - Journal of the …, 2022 - ACS Publications
As a strategy to design stable but highly reactive metal nitrido species, we have synthesized
a manganese (V) nitrido complex bearing a bulky corrole ligand,[MnV (N)(TTPPC)]−(1 …
a manganese (V) nitrido complex bearing a bulky corrole ligand,[MnV (N)(TTPPC)]−(1 …