Femtosecond symmetry breaking and coherent relaxation of methane cations via x-ray spectroscopy

E Ridente, D Hait, EA Haugen, AD Ross, DM Neumark… - Science, 2023 - science.org
Understanding the relaxation pathways of photoexcited molecules is essential to gain
atomistic-level insight into photochemistry. We performed a time-resolved study of ultrafast …

Reinvented: An Attosecond Chemist

SR Leone - Annual Review of Physical Chemistry, 2023 - annualreviews.org
Attosecond science requires a substantial rethinking of how to make measurements on very
short timescales; how to acquire the necessary equipment, technology, and personnel; and …

[HTML][HTML] Ultrafast hole deformation revealed by molecular attosecond interferometry

Y Huang, J Zhao, Z Shu, Y Zhu, J Liu, W Dong… - Ultrafast …, 2021 - spj.science.org
Understanding the evolution of molecular electronic structures is the key to explore and
control photochemical reactions and photobiological processes. Subjected to strong laser …

Quantum Coherence Effect in the Interaction of Light and Molecules

Y Song, C Qin, S Dong, X Li, A Wei… - Laser & Photonics …, 2024 - Wiley Online Library
Understanding the quantum coherence effects is crucial for their promising applications,
such as engineering artificial photosynthesis, manipulating chemical reactions, and …

Table-top X-ray spectroscopy of benzene radical cation

M Epshtein, V Scutelnic, Z Yang, T Xue… - The Journal of …, 2020 - ACS Publications
Ultrafast table-top X-ray spectroscopy at the carbon K-edge is used to measure the X-ray
spectral features of benzene radical cations (Bz+). The ground state of the cation is prepared …

Core-valence attosecond transient absorption spectroscopy of polyatomic molecules

NV Golubev, J Vaníček, AI Kuleff - Physical Review Letters, 2021 - APS
Tracing ultrafast processes induced by interaction of light with matter is often very
challenging. In molecular systems, the initially created electronic coherence becomes …

Ultrafast geometrical reorganization of a methane cation upon sudden ionization: an isotope effect on electronic non-equilibrium quantum dynamics

CEM Gonçalves, RD Levine, F Remacle - … Chemistry Chemical Physics, 2021 - pubs.rsc.org
The ultrafast structural, Jahn–Teller (JT) driven, electronic coherence mediated quantum
dynamics in the CH4+ and CD4+ cations that follows sudden ionization using an XUV …

Role of spin-orbit coupling in high-order harmonic generation revealed by supercycle Rydberg trajectories

N Mayer, S Beaulieu, Á Jiménez-Galán… - Physical Review Letters, 2022 - APS
High-harmonic generation is typically thought of as a sub-laser-cycle process, with the
electron's excursion in the continuum lasting a fraction of the optical cycle. However, it was …

[HTML][HTML] Characterizing coherences in chemical dynamics with attosecond time-resolved x-ray absorption spectroscopy

Y Kobayashi, SR Leone - The Journal of Chemical Physics, 2022 - pubs.aip.org
Coherence can drive wave-like motion of electrons and nuclei in photoexcited systems,
which can yield fast and efficient ways to exert materials' functionalities beyond the …

Vibronic Correlations in Molecular Strong-Field Dynamics

M Labeye, C Lévêque, F Risoud… - The Journal of …, 2024 - ACS Publications
We investigate the ultrafast vibronic dynamics triggered by intense femtosecond infrared
pulses in small molecules. Our study is based on numerical simulations performed with 2D …