Progress in uranium chemistry: driving advances in front-end nuclear fuel cycle forensics

KJ Pastoor, RS Kemp, MP Jensen… - Inorganic Chemistry, 2021 - ACS Publications
The front-end of the nuclear fuel cycle encompasses several chemical and physical
processes used to acquire and prepare uranium for use in a nuclear reactor. These same …

Quantifying Morphological Features of α-U3O8 with Image Analysis for Nuclear Forensics

AM Olsen, B Richards, I Schwerdt, S Heffernan… - Analytical …, 2017 - ACS Publications
Morphological changes in U3O8 based on calcination temperature have been quantified
enabling a morphological feature to serve as a signature of processing history in nuclear …

Nuclear forensics investigation of morphological signatures in the thermal decomposition of uranyl peroxide

IJ Schwerdt, A Olsen, R Lusk, S Heffernan… - Talanta, 2018 - Elsevier
The analytical techniques typically utilized in a nuclear forensic investigation often provide
limited information regarding the process history and production conditions of interdicted …

Impact of Controlled Storage Conditions on the Hydrolysis and Surface Morphology of Amorphous-UO3

AB Hanson, IJ Schwerdt, CA Nizinski, RN Lee… - ACS …, 2021 - ACS Publications
The hydration and morphological effects of amorphous (A)-UO3 following storage under
varying temperature and relative humidity have been investigated. This study provides …

Energetics of oxidation and formation of uranium mononitride

VG Goncharov, J Liu, A van Veelen… - Journal of Nuclear …, 2022 - Elsevier
Uranium mononitride (UN) is an advanced nuclear fuel currently being considered for use in
several generation IV fast and thermal neutron spectrum core designs, with additional …

Parabolic oxidation kinetics of a plutonium alloy at room temperature

SB Donald, JA Stanford, JM Haschke, DD Ashley… - Corrosion …, 2021 - Elsevier
Auger electron spectroscopy (AES) was used to characterize the oxide scale formed on an∼
0.5 wt.% Ga plutonium metal alloy. Analysis of changes to the characteristic Auger …

Identification and Decomposition of Uranium Oxychloride Phases in Oxygen-Exposed UCl3 Salt Compositions

BW Tuffy, NR Birkner, J Schorne-Pinto… - The Journal of …, 2023 - ACS Publications
Complementary X-ray absorption fine structure (XAFS) spectroscopy and Raman
spectroscopy studies were conducted on several UCl3 concentrations in several chloride …

Dependence of UO2 surface morphology on processing history within a single synthetic route

EC Abbott, A Brenkmann, C Galbraith, J Ong… - Radiochimica …, 2019 - degruyter.com
This study aims to determine forensic signatures for processing history of UO2 based on
modifications in intermediate materials within the uranyl peroxide route. Uranyl peroxide …

Hydration of α-UO 3 following storage under controlled conditions of temperature and relative humidity

MP Wilkerson, SC Hernandez, WT Mullen… - Dalton …, 2020 - pubs.rsc.org
Changes in chemical speciation of uranium oxides following storage under varied
conditions of temperature and relative humidity are valuable for characterizing material …

Characterization of the aerosol-based synthesis of uranium particles as a potential reference material for microanalytical methods

R Middendorp, M Durr, A Knott, F Pointurier… - Analytical …, 2017 - ACS Publications
A process for production of micrometer-sized particles composed of uranium oxide using
aerosol spray pyrolysis is characterized with respect to the various production parameters …