The Nitrogen Bond, or the Nitrogen-Centered Pnictogen Bond: The Covalently Bound Nitrogen Atom in Molecular Entities and Crystals as a Pnictogen Bond Donor

PR Varadwaj, A Varadwaj, HM Marques, K Yamashita - Compounds, 2022 - mdpi.com
The nitrogen bond in chemical systems occurs when there is evidence of a net attractive
interaction between the electrophilic region associated with a covalently or coordinately …

Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Synthesis, spectroscopic investigation, molecular docking, ADME/T toxicity predictions, and DFT study of two trendy ortho vanillin-based scaffolds

D Majumdar, A Dubey, A Tufail, D Sutradhar, S Roy - Heliyon, 2023 - cell.com
In this article, we have synthesized two contemporary ortho-vanillin-based Salen-type
ligands (H 2 L 1/H 2 L 2) characterized by modern spectroscopic tools. EDX analysis …

The halogen bond with isocyano carbon reduces isocyanide odor

AS Mikherdov, AS Novikov, VP Boyarskiy… - Nature …, 2020 - nature.com
Predominantly, carbon atoms of various species function as acceptors of noncovalent
interactions when they are part of a π-system. Here, we report on the discovery of a halogen …

Effect of oxygen vacancy influenced by CeO2 morphology on the methanol catalytic reforming for hydrogen production

L Xie, B Hu, R Shu, Z Tian, Y Chen, C Wang - International Journal of …, 2023 - Elsevier
Methanol reforming has been a popular pathway to produce hydrogen due to the high
hydrogen storage density of methanol. CeO 2 as the support is widely used for catalytic …

Studies of Nature of Uncommon Bifurcated I–I···(I–M) Metal-Involving Noncovalent Interaction in Palladium (II) and Platinum (II) Isocyanide Cocrystals

M Bulatova, DM Ivanov, JM Rautiainen… - Inorganic …, 2021 - ACS Publications
Two isostructural trans-[MI2 (CNXyl) 2]· I2 (M= Pd or Pt; CNXyl= 2, 6-dimethylphenyl
isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal …

Experimental and computational tuning of metalla-N-heterocyclic carbenes at palladium (ii) and platinum (ii) centers

MV Kashina, KV Luzyanin, EA Katlenok… - Dalton …, 2022 - pubs.rsc.org
Palladium (II) and platinum (II) complexes featuring metalla-N-heterocyclic carbenes (7–12)
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …

Challenging the electrostatic σ‐hole picture of halogen bonding using minimal models and the interacting quantum atoms approach

F Jiménez‐Grávalos, M Gallegos… - Journal of …, 2021 - Wiley Online Library
Among the different noncovalent interactions, halogen bonds have captured wide attention
in the last years. Their stability has been rationalized in electrostatic terms by appealing to …

Modulation of luminescence properties for [cyclometalated]-Pt II (isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes

SA Katkova, KV Luzyanin, AS Novikov… - New Journal of …, 2021 - pubs.rsc.org
Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo-and
iodosubstituted perfluorinated arenes to give 1: 1 adducts. X-FArenes in these co-crystals …

Non-covalent interactions in polymers

AS Novikov - Polymers, 2023 - mdpi.com
Non-covalent interactions are one of the key topics in modern chemical science. These inter-
and intramolecular weak interactions (eg, hydrogen, halogen, and chalcogen bonds …