Ambient ionization mass spectrometry: recent developments and applications

CL Feider, A Krieger, RJ DeHoog… - Analytical chemistry, 2019 - ACS Publications
The early 2000s brought a new age in the field of mass spectrometry (MS) with the
introduction of ambient ionization MS techniques. As defined by one of its early visionaries …

Measuring the surface tension of atmospheric particles and relevant mixtures to better understand key atmospheric processes

M El Haber, V Gérard, J Kleinheins… - Chemical …, 2024 - ACS Publications
Aerosol and aqueous particles are ubiquitous in Earth's atmosphere and play key roles in
geochemical processes such as natural chemical cycles, cloud and fog formation, air …

Reaction acceleration promoted by partial solvation at the gas/solution interface

L Qiu, Z Wei, H Nie, RG Cooks - ChemPlusChem, 2021 - Wiley Online Library
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and
sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent …

The role of analyte concentration in accelerated reaction rates in evaporating droplets

CJ Chen, ER Williams - Chemical science, 2023 - pubs.rsc.org
Accelerated reactions in microdroplets have been reported for a wide range of reactions with
some microdroplet reactions occurring over a million times faster than the same reaction in …

Emerging investigator series: surfactants, films, and coatings on atmospheric aerosol particles: a review

KA Wokosin, EL Schell, JA Faust - Environmental Science …, 2022 - pubs.rsc.org
Surfactants are surface-active molecules or ions that can often be found at the surface of
atmospheric aerosol particles. Some surfactants, such as biomolecules in marine aerosol …

Chemical reaction monitoring by ambient mass spectrometry

J Sun, Y Yin, W Li, O Jin, N Na - Mass Spectrometry Reviews, 2022 - Wiley Online Library
Chemical reactions conducted in different media (liquid phase, gas phase, or surface) drive
developments of versatile techniques for the detection of intermediates and prediction of …

Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids

KH Bates, DJ Jacob, JD Cope, X Chen… - Environmental …, 2023 - pubs.rsc.org
Atmospheric chemistry models generally assume organic aerosol (OA) to be
photochemically inert. Recent mechanisms for the oxidation of biogenic isoprene, a major …

Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products

B Witkowski, M Al-Sharafi, K Błaziak… - … science & technology, 2023 - ACS Publications
The reaction of hydroxyl radicals (OH) with a water-soluble fraction of the α-pinene
secondary organic aerosol (SOA) was investigated using liquid chromatography coupled …

A physicochemical consideration of prebiotic microenvironments for self-assembly and prebiotic chemistry

A Saha, R Yi, AC Fahrenbach, A Wang, TZ Jia - Life, 2022 - mdpi.com
The origin of life on Earth required myriads of chemical and physical processes. These
include the formation of the planet and its geological structures, the formation of the first …

Review of air-water interface adsorption and reactions between trace gaseous organic and oxidant compounds

AV Karre, KT Valsaraj, V Vasagar - Science of The Total Environment, 2023 - Elsevier
The surface chemistry of the atmospheric aerosol through homogeneous and
heterogeneous catalytic reactions in the bulk water and the air-water surface is reviewed …