Transition metal-catalyzed living radical polymerization: toward perfection in catalysis and precision polymer synthesis

M Ouchi, T Terashima, M Sawamoto - Chemical Reviews, 2009 - ACS Publications
Precision control of radical polymerization, or living radical polymerization, has been among
the most important and long-waited subjects in polymer chemistry and macromolecular …

Synthesis of functional polymers by post‐polymerization modification

MA Gauthier, MI Gibson, HA Klok - … Chemie International Edition, 2009 - Wiley Online Library
Post‐polymerization modification is based on the direct polymerization or copolymerization
of monomers bearing chemoselective handles that are inert towards the polymerization …

50th Anniversary Perspective: Polymer Functionalization

E Blasco, MB Sims, AS Goldmann, BS Sumerlin… - …, 2017 - ACS Publications
The translation of small molecule chemistries into efficient methodologies for polymer
functionalization spans several decades, enabling critical advances in soft matter materials …

Azlactone-functionalized polymers as reactive platforms for the design of advanced materials: Progress in the last ten years

ME Buck, DM Lynn - Polymer Chemistry, 2012 - pubs.rsc.org
Polymers functionalized with azlactone (or oxazolone) functionality have become
increasingly useful for the rapid and modular design of functional materials. Because …

Synthesis of reactive telechelic polymers based on pentafluorophenyl esters

PJ Roth, KT Wiss, R Zentel, P Theato - Macromolecules, 2008 - ACS Publications
A diazo initiator and a chain transfer agent (CTA), both containing a pentafluorophenyl (PFP)
activated ester, were synthesized. In a RAFT polymerization using the functionalized chain …

Controllable synthesis of poly (N-vinylpyrrolidone) and its block copolymers by atom transfer radical polymerization

X Lu, S Gong, L Meng, C Li, S Yang, L Zhang - Polymer, 2007 - Elsevier
At room temperature atom transfer radical polymerization (ATRP) of N-vinylpyrrolidone
(NVP) was carried out using 5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetra-azacyclo …

Well-defined polymers with activated ester and protected aldehyde side chains for bio-functionalization

J Hwang, RC Li, HD Maynard - Journal of Controlled Release, 2007 - Elsevier
Polymers with reactive side chains and narrow molecular weight distributions were
synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, and …

Surface-anchored poly (2-vinyl-4, 4-dimethyl azlactone) brushes as templates for enzyme immobilization

SP Cullen, IC Mandel, P Gopalan - Langmuir, 2008 - ACS Publications
We explored surface-anchored poly (2-vinyl-4, 4-dimethyl azlactone)(PVDMA) brushes as
potential templates for protein immobilization. The brushes were grown using atom transfer …

Sequential conversion of orthogonally functionalized diblock copolymers based on pentafluorophenyl esters

K Nilles, P Theato - Journal of Polymer Science Part A …, 2010 - Wiley Online Library
Statistic and block copolymers exhibiting activated ester side groups were synthesized by
reversible addition‐fragmentation chain transfer polymerization in the presence of cumyl …

Keto-functionalized polymer scaffolds as versatile precursors to polymer side-chain conjugates

J Liu, RC Li, GJ Sand, V Bulmus, TP Davis… - …, 2013 - ACS Publications
A new methacrylate monomer with a reactive ketone side chain, 2-(4-oxopentanoate) ethyl
methacrylate (PAEMA), was synthesized and subsequently polymerized by reversible …