Post‐polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization …
The translation of small molecule chemistries into efficient methodologies for polymer functionalization spans several decades, enabling critical advances in soft matter materials …
ME Buck, DM Lynn - Polymer Chemistry, 2012 - pubs.rsc.org
Polymers functionalized with azlactone (or oxazolone) functionality have become increasingly useful for the rapid and modular design of functional materials. Because …
PJ Roth, KT Wiss, R Zentel, P Theato - Macromolecules, 2008 - ACS Publications
A diazo initiator and a chain transfer agent (CTA), both containing a pentafluorophenyl (PFP) activated ester, were synthesized. In a RAFT polymerization using the functionalized chain …
X Lu, S Gong, L Meng, C Li, S Yang, L Zhang - Polymer, 2007 - Elsevier
At room temperature atom transfer radical polymerization (ATRP) of N-vinylpyrrolidone (NVP) was carried out using 5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetra-azacyclo …
J Hwang, RC Li, HD Maynard - Journal of Controlled Release, 2007 - Elsevier
Polymers with reactive side chains and narrow molecular weight distributions were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, and …
SP Cullen, IC Mandel, P Gopalan - Langmuir, 2008 - ACS Publications
We explored surface-anchored poly (2-vinyl-4, 4-dimethyl azlactone)(PVDMA) brushes as potential templates for protein immobilization. The brushes were grown using atom transfer …
K Nilles, P Theato - Journal of Polymer Science Part A …, 2010 - Wiley Online Library
Statistic and block copolymers exhibiting activated ester side groups were synthesized by reversible addition‐fragmentation chain transfer polymerization in the presence of cumyl …
A new methacrylate monomer with a reactive ketone side chain, 2-(4-oxopentanoate) ethyl methacrylate (PAEMA), was synthesized and subsequently polymerized by reversible …