Stereoselective formation of boron-stereogenic organoboron derivatives

A Abdou-Mohamed, C Aupic, C Fournet… - Chemical Society …, 2023 - pubs.rsc.org
Four-coordinate organoboron derivatives present interesting chemical, physical, biological,
electronical, and optical properties. Given the increasing demand for the synthesis of smart …

Electronic communication and negative binding cooperativity in diborylated bithiophenes

A Sundararaman, K Venkatasubbaiah… - Journal of the …, 2006 - ACS Publications
The bifunctional conjugated organoboranes Ar2B bt BAr2, which contain 2, 2 '-bithiophene
(bt) linkers and different aryl substituents on boron (3: Ar= pt BuC6H4; 4: Ar= C6F5; 5: Ar …

Direct Synthetic Route to Functionalized 1, 2‐Azaborinines

H Braunschweig, K Geetharani… - Angewandte Chemie …, 2014 - Wiley Online Library
A new catalytic synthetic route to functionalized 1, 2‐azaborinines has been developed by
the [2+ 2]/[2+ 4] cycloaddition reactions of di‐tert‐butyliminoboranes and alkynes in …

Diorganotin (IV) dithiocarbamate complexes as chromogenic sensors of anion binding

JP Fuentes-Martínez, I Toledo-Martínez… - Polyhedron, 2009 - Elsevier
One dinuclear chlorodiphenyltin (IV) dithiocarbamate complex (1) and four mononuclear
complexes of general formula Ph2Sn (S2CNR) Cl (2, 3, 5, and 6) have been synthesized …

Reactions of 3, 5-pyrazoledicarboxylic acid with organotin chlorides and oxides. Coordination polymers containing organotin macrocycles

V Chandrasekhar, R Thirumoorthi - Organometallics, 2009 - ACS Publications
The reaction of 3, 5-pyrazoledicarboxylic acid (LH3) with di-and triorganotin substrates has
been investigated. The reaction of LH3 with (PhCH2) 2SnCl2 afforded a macrocycle …

9-Ferrocenyl-9-borafluorene A Redox-Switchable Main Group Lewis Acid

L Kaufmann, H Vitze, M Bolte, HW Lerner… - …, 2008 - ACS Publications
9-Ferrocenyl-9-borafluorene (FcBC12H8; 3) is readily accessible from FcHgCl and
BrBC12H8. The 9-borafluorenyl substituent is bent out of the plane of the cyclopentadienyl …

Simultaneous fluoride binding to ferrocene-based heteronuclear bidentate Lewis acids

R Boshra, K Venkatasubbaiah, A Doshi… - Inorganic …, 2007 - ACS Publications
A series of μ2-fluoro-bridged heteronuclear bidentate Lewis acid complexes [K (18-crown-6)
THF]+[Fc (BMeF)(SnMe2Cl) F]-(1-2F),[K (18-crown-6) THF]+[Fc (BMeF)(SnMe2F) F]-(1 …

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)borylbenzenes and o-(Difluorosilyl)borylbenzenes, and Their Fluoride Ion Affinities

J Shimada, A Tani, C Hanazato, T Masuyama… - ACS …, 2022 - ACS Publications
Herein, we report detailed studies on a series of o-(silyl)(boryl) benzenes (1–4), in which the
two Lewis acid centers consisting of silicon and boron atoms are linked via an o-phenylene …

Fluoride anion binding by cyclic boronic esters: influence of backbone chelate on receptor integrity

C Bresner, JK Day, ND Coombs, IA Fallis… - Dalton …, 2006 - pubs.rsc.org
A systematic investigation of fluoride anion binding properties as a function of chelate
backbone has been carried out for ferrocene functionalised boronic esters of the types FcB …

Syntheses and anion binding capabilities of bis (diarylboryl) ferrocenes and related systems

MJ Kelly, AEJ Broomsgrove, IR Morgan, I Siewert… - …, 2013 - ACS Publications
Isomeric diborylated ferrocenes featuring 1, 1′-, 1, 2-, and 1, 3-substitution patterns have
been targeted via a combination of electrophilic aromatic substitution and directed ortho …