The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

An electrochemically driven nickel-catalyzed enantioselective reductive cross-coupling of
aryl aziridines with alkenyl bromides has been developed, affording enantioenriched β-aryl …

Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to
join two electrophiles. These reactions have proven particularly useful for the coupling of sec …

Herein, we designed a reaction for the desymmetrization–addition of cyclopropenes to
imines by leveraging the synergy between photoredox and asymmetric cobalt catalysis. This …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formations have been
made with nickel-catalyzed cross-coupling of racemic alkyl electrophiles with organometallic …

Enantioselective metallaphotoredox catalysis, which combines photoredox catalysis and
asymmetric transition-metal catalysis, has become an effective approach to achieve …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Transition metal-catalysed asymmetric coupling has been established as a robust tool for
constructing complex organic molecules. Although this area has been extensively studied …