Photocatalytic late-stage C–H functionalization

P Bellotti, HM Huang, T Faber, F Glorius - Chemical Reviews, 2023 - ACS Publications
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Sulfonium Salts as Acceptors in Electron Donor‐Acceptor Complexes

L van Dalsen, RE Brown… - Angewandte Chemie …, 2023 - Wiley Online Library
The photoactivation of electron donor‐acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. Electron donor …

Organothianthrenium salts: synthesis and utilization

H Meng, MS Liu, W Shu - Chemical Science, 2022 - pubs.rsc.org
Organothianthrenium salts are a class of compounds containing a positively charged sulfur
atom and a neutral sulfur atom. Over the past years, organothianthrenium salts have been …

Intermolecular Metal‐Free Cyclopropanation and Aziridination of Alkenes with XH2 (X=N, C) by Thianthrenation**

MS Liu, HW Du, JF Cui, W Shu - Angewandte Chemie, 2022 - Wiley Online Library
Three‐membered cyclic structures are widely existing in natural products and serve as
enabling intermediates in organic synthesis. However, the efficient and straightforward …

Visible-Light-Driven Synthesis of Aryl Xanthates and Aryl Dithiocarbamates via an Electron Donor–Acceptor Complex

M Zhang, B Wang, Y Cao, Y Liu, Z Wang… - Organic Letters, 2022 - ACS Publications
Herein, we report a facile, efficient, and practical protocol that enables the preparation of aryl
xanthates and aryl dithiocarbamates from functionalized dibenzothiophenium salts via a …

Thianthrenium-Enabled Phosphorylation of Aryl C–H Bonds via Electron Donor–Acceptor Complex Photoactivation

H Xu, X Li, Y Dong, S Ji, J Zuo, J Lv, D Yang - Organic Letters, 2023 - ACS Publications
An efficient strategy for the preparation of aryl phosphonates via blue-light-promoted single
electron transfer process of an EDA complex between phosphites and thianthrenium salts …

A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes

JD Lasso, DJ Castillo-Pazos, JM Salgado… - Journal of the …, 2024 - ACS Publications
Catalytic electron donor–acceptor (EDA) complexes have recently emerged as a powerful
and sustainable alternative to iridium-and ruthenium-based photoredox synthetic methods …

Cu-Mediated Thianthrenation and Phenoxathiination of Arylborons

XY Chen, YN Li, Y Wu, J Bai, Y Guo… - Journal of the American …, 2023 - ACS Publications
Great success in synthetic chemistry is motivated by the development of novel and reactive
linchpins for carbon–carbon and carbon–heteroatom bond formation reactions, which has …

Radical C–H Sulfonation of Arenes: Its Applications on Bioactive and DNA-Encoded Molecules

Y Zhang, S Xia, W Shi, B Lin, X Su, W Lu, X Wu… - Organic …, 2022 - ACS Publications
The photocatalyst-free electron donor–acceptor (EDA) complex photochemistry was
deemed to expand the potential of photodriven radical chemistry. Here, we report a cross …

Catalyst-Free C(sp2)-H Borylation through Aryl Radical Generation from Thiophenium Salts via Electron Donor–Acceptor Complex Formation

B Li, K Wang, H Yue, A Drichel, J Lin, Z Su… - Organic …, 2022 - ACS Publications
Aryl borates lie at the heart of carbon–carbon bond couplings, and they are widely applied to
the synthesis of functional materials, pharmaceutical compounds, and natural products …