Selective activation of alkanes by gas-phase metal ions

J Roithova, D Schroder - Chemical reviews, 2010 - ACS Publications
The importance of the selective activation of alkanes for science and technology in the
forthcoming decades does not need to be explicitly pointed out in this thematic issue of …

Applications of electrospray ionization mass spectrometry in mechanistic studies and catalysis research

D Schröder - Accounts of chemical research, 2012 - ACS Publications
Mechanistic studies form the basis for a better understanding of chemical processes, helping
researchers develop more sustainable reactions by increasing the yields of the desired …

Characterization of reaction intermediates by ion spectroscopy

J Roithová - Chemical Society Reviews, 2012 - pubs.rsc.org
In the last decade, we have experienced massive progress in spectroscopic methods for
mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a …

Actinide colloids and particles of environmental concern

C Walther, MA Denecke - Chemical reviews, 2013 - ACS Publications
The radioecological relevance of actinide particles 1 did not first become a matter of concern
following the nuclear accidents at Fukushima, Chernobyl, or Three Mile Island. Public and …

Deprotonation of p-Hydroxybenzoic Acid: Does Electrospray Ionization Sample Solution or Gas-Phase Structures?

D Schröder, M Budesinsky… - Journal of the American …, 2012 - ACS Publications
Despite the simplicity of the molecule, the site of single deprotonation of p-hydroxybenzoic
acid upon electrospray ionization (ESI) has recently formed a subject of debate in this …

Role of gold (I) α-oxo carbenes in the oxidation reactions of alkynes catalyzed by gold (I) complexes

J Schulz, L Jasikova, A Skriba… - Journal of the American …, 2014 - ACS Publications
The gas phase structures of gold (I) complexes formed by intermolecular oxidation of
selected terminal (phenylacetylene) and internal alkynes (2-butyne, 1-phenylpropyne …

Gas-phase uranyl, neptunyl, and plutonyl: hydration and oxidation studied by experiment and theory

D Rios, MC Michelini, AF Lucena, J Marçalo… - Inorganic …, 2012 - ACS Publications
The following monopositive actinyl ions were produced by electrospray ionization of
aqueous solutions of AnVIO2 (ClO4) 2 (An= U, Np, Pu): UVO2+, NpVO2+, PuVO2+, UVIO2 …

Association and Dissociation of Grignard Reagents RMgCl and Their Turbo Variant RMgCl⋅ LiCl

C Schnegelsberg, S Bachmann… - … A European Journal, 2016 - Wiley Online Library
Grignard reagents RMgCl and their so‐called turbo variant, the highly reactive RMgCl⋅ LiCl,
are of exceptional synthetic utility. Nevertheless, it is still not fully understood which species …

Speciation studies of metals in trace concentrations: the mononuclear uranyl (VI) hydroxo complexes

B Drobot, A Bauer, R Steudtner, S Tsushima… - Analytical …, 2016 - ACS Publications
A direct luminescence spectroscopic experimental setup for the determination of complex
stability constants of mononuclear uranyl (VI) hydrolysis species is presented. The …

New insights into the extraction of uranium (VI) by an N, N-dialkylamide

F Rodrigues, G Ferru, L Berthon, N Boubals… - Molecular …, 2014 - Taylor & Francis
This paper presents the methodology developed in order to thoroughly characterise a
solvent extraction system containing high solute concentrations. The chemical system …