Studies on coordination chemistry published over the last 20 years, have led to increased
interest in coordination polymers (CPs). This interest has been generated not only by the …

The tetrel bond (TB) recruits an element drawn from the C, Si, Ge, Sn, Pb family as electron
acceptor in an interaction with a partner Lewis base. The underlying principles that explain …

Spontaneous self-assembly in the supramolecular entity is one of the enthralling synthetic
routes. It produces disparate structure crystal complexes after selecting suitable ML …

In this work we report a new Hg (II) coordination compound [Hg (HL)(SCN) 2], which was
readily obtained from a mixture of Hg (SCN) 2 and N'-(1-(pyridin-2-yl) ethylidene) …

The properties of the bond between a N-ligand and a Lewis acid containing a σ–hole are
studied by quantum chemical methods. Interactions considered include pnicogen bonds …

In this work we have synthesized and characterized two new mononuclear nickel (II)
complexes [NiLI]· CH3CN (1· CH3CN) and [Ni (H2LII)(NCS) 2]· 0.5 H2O (2· 0.5 H2O) …

A new coordination polymer [Hg (LI) I] n (1) and a new discrete coordination complex [Hg
(HLII) I2](2) are synthesized and X-ray characterized. The existence of positive π-holes at …

Three new PbII complexes [Pb (LI)(SCN)] n,{[Pb (LII)](SCN)} n and {[Pb (HLIII)(SCN)](SCN)}
n (HLI= N′-phenyl (pyridin-2-yl) methylene-N-phenylthiosemicarbazide, HLII= N′-amino …

The pairing of TFH3 with a TH2CH3− anion, where T represents tetrel atoms C, Si, Ge, Sn,
Pb, results in a strong direct interaction between the two T atoms. The interaction energy is …

In this work, we have directed our attention to the evaluation of closely related bis-pyridyl
ligands N′-(pyridin-2-ylmethylene) picolinohydrazide (HLI), N′-(pyridin-2-ylmethylene) …