Confinement of luminescent guests in metal–organic frameworks: understanding pathways from synthesis and multimodal characterization to potential applications of …
This review gives an authoritative, critical, and accessible overview of an emergent class of
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …
A critical assessment on calculating vibrational spectra in nanostructured materials
Vibrational spectroscopy is an omnipresent spectroscopic technique to characterize
functional nanostructured materials such as zeolites, metal–organic frameworks (MOFs) …
functional nanostructured materials such as zeolites, metal–organic frameworks (MOFs) …
The role of phonons in switchable MOFs: a model material perspective
The large cell volume changes of switchable metal–organic frameworks (MOFs) render them
as promising functional materials. Low-frequency phonon modes are known to influence the …
as promising functional materials. Low-frequency phonon modes are known to influence the …
Unfolding the terahertz spectrum of soft porous crystals: rigid unit modes and their impact on phase transitions
Phase transitions in flexible metal–organic frameworks or soft porous crystals are mediated
by low-frequency phonons or rigid-unit modes. The alteration of specific building blocks may …
by low-frequency phonons or rigid-unit modes. The alteration of specific building blocks may …
Dynamic three-dimensional structures of a metal–organic framework captured with femtosecond serial crystallography
Crystalline systems consisting of small-molecule building blocks have emerged as
promising materials with diverse applications. It is of great importance to characterize not …
promising materials with diverse applications. It is of great importance to characterize not …
Structural phase transitions in flexible DUT-8 (Ni) under high hydrostatic pressure
The behaviours of the open pore (op) and closed pore (cp) phases of the flexible Ni2 (ndc) 2
(dabco)(ndc–2, 6-naphthalene dicarboxylate, dabco–1, 4-diazabicyclo [2.2. 2] octane, DUT …
(dabco)(ndc–2, 6-naphthalene dicarboxylate, dabco–1, 4-diazabicyclo [2.2. 2] octane, DUT …
Experimental evidence for vibrational entropy as driving parameter of flexibility in the metal–organic framework ZIF-4 (Zn)
KT Butler, P Vervoorts, MG Ehrenreich… - Chemistry of …, 2019 - ACS Publications
Large structural flexibility in some metal–organic frameworks (MOFs) is not only fascinating
from a fundamental point of view but offers exciting opportunities in the areas of gas sensing …
from a fundamental point of view but offers exciting opportunities in the areas of gas sensing …
Phononic modulation of spin-lattice relaxation in molecular qubit frameworks
A Zhou, D Li, M Tan, Y Lv, S Pang, X Zhao… - Nature …, 2024 - nature.com
The solid-state integration of molecular electron spin qubits could promote the advancement
of molecular quantum information science. With highly ordered structures and rational …
of molecular quantum information science. With highly ordered structures and rational …
Computational Modeling of Reticular Materials: The Past, the Present, and the Future
Reticular materials rely on a unique building concept where inorganic and organic building
units are stitched together giving access to an almost limitless number of structured ordered …
units are stitched together giving access to an almost limitless number of structured ordered …
Raman Evidence of Multiple Adsorption Sites and Structural Transformation in ZIF-4
The zeolitic imidazolate framework, ZIF-4, exhibits soft porosity and is known to show pore
volume changes with temperatures, pressures, and guest adsorption. However, the …
volume changes with temperatures, pressures, and guest adsorption. However, the …