Recent advances in phosphorescent Pt (II) complexes featuring metallophilic interactions: properties and applications

A Aliprandi, D Genovese, M Mauro… - Chemistry Letters, 2015 - academic.oup.com
Supramolecular weak interactions can be used for preparing functional self-assembled
architectures by powerful bottom-up approaches. In particular, when closed-shell …

Transition metal chain complexes supported by soft donor assembling ligands

P Braunstein, AA Danopoulos - Chemical Reviews, 2021 - ACS Publications
The chemistry of discrete molecular chains constituted by metals in low oxidation states,
displaying metal–metal proximity and stabilized by suitable metal-bridging, assembling …

Cyclometalated platinum (II) complexes simultaneously catalyze the cross-linking of polysiloxanes and function as luminophores

MV Dobrynin, EV Sokolova, MA Kinzhalov… - ACS Applied Polymer …, 2021 - ACS Publications
A family of the C, N-cyclometalated species [Pt (ppy) Cl (PPh3)],[Pt (ppy) Cl (CNCy)],[Pt
(ppy)(CNCy)(PPh3)](OTf), and [Pt (ppy)(CNCy) 2](BF4)(ppy= 2-phenylpyridinato-C 2, N; Cy …

Luminescent cyclometalated-pentafluorophenyl PtII, PtIV and heteropolynuclear complexes

JR Berenguer, E Lalinde, MT Moreno - Coordination Chemistry Reviews, 2018 - Elsevier
Platinum complexes bearing cyclometalating ligands possess impressive photophysical
properties that make these compounds desirable for optoelectronic and photonic …

Half-Sandwich Cyclometalated RhIII Complexes Bearing Thiolate Ligands: Biomolecular Interactions and In Vitro and In Vivo Evaluations

A Nahaei, Z Mandegani, S Chamyani… - Inorganic …, 2022 - ACS Publications
A class of cyclometalated RhIII complexes [Cp* Rh (ppy)(SR)] bearing thiolate ligands, Cp*=
pentamethylcyclopentadienyl, ppy= 2-phenylpyridinate, and R= pyridyl (Spy, 2), pyrimidyl …

Unusual Metal–Metal Bonding in a Dinuclear Pt–Au Complex: Snapshot of a Transmetalation Process

M Baya, Ú Belío, I Fernández, S Fuertes… - Angewandte …, 2016 - Wiley Online Library
Abstract The dinuclear Pt–Au complex [(CNC)(PPh3) Pt Au (PPh3)](ClO4)(2)(CNC= 2, 6‐
diphenylpyridinate) was prepared. Its crystal structure shows a rare metal–metal bonding …

Luminescent cycloplatinated complexes with biologically relevant phosphine ligands: optical and cytotoxic properties

G Millán, N Giménez, R Lara, JR Berenguer… - Inorganic …, 2019 - ACS Publications
Two series of neutral luminescent pentafluorophenyl cycloplatinated (II) complexes [Pt (C^
N)(C6F5) L][C^ N= C-deprotonated 2-phenylpyridine (ppy; a), 2-(2, 4-difluorophenylpyridine …

An extended chain and trinuclear complexes based on Pt (II)–M (M= Tl (I), Pb (II)) bonds: contrasting photophysical behavior

J Forniés, N Giménez, S Ibáñez, E Lalinde… - Inorganic …, 2015 - ACS Publications
The syntheses and structural characterizations of a Pt–Tl chain [{Pt (bzq)(C6F5) 2} Tl
(Me2CO)] n 1 and two trinuclear Pt2M clusters (NBu4)[{Pt (bzq)(C6F5) 2} 2Tl] 2 and [{Pt …

Synthesis, biological evaluation, and molecular docking studies on the DNA binding interactions of platinum (II) rollover complexes containing phosphorus donor …

M Fereidoonnezhad, M Niazi… - …, 2017 - Wiley Online Library
Cyclometalated rollover complexes of the type [PtMe (κ2N, C‐bipyO‐H)(L)][bipyO‐H=
cyclometalated 2, 2′‐bipyridine N‐oxide; L= tricyclohexylphosphine (PCy3, 2 a), 2 …

Luminescence properties of some monomeric and dimeric cycloplatinated (II) complexes containing biphosphine ligands

RB Aghakhanpour, SM Nabavizadeh, M Rashidi… - Dalton …, 2015 - pubs.rsc.org
The starting complexes [PtCl (C^ N)(dmso)], in which C^ N is either ppy= 2-phenylpyridinate,
1a, or bhq= 7, 8-benzo [h] quinolinate, 2a, were prepared by a known method using the …