Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Recent advances in catalytic sequential reactions involving hydroelement addition to carbon–carbon multiple bonds

X Zeng - Chemical Reviews, 2013 - ACS Publications
Sequential reactions, through the incorporation of several distinct transformations into one
single sequence, are one of the most powerful synthetic tools in modern organic chemistry …

Visible light driven water splitting in a molecular device with unprecedentedly high photocurrent density

Y Gao, X Ding, J Liu, L Wang, Z Lu, L Li… - Journal of the American …, 2013 - ACS Publications
A molecular water oxidation catalyst (2) has been synthesized and immobilized together
with a molecular photosensitizer (1) on nanostructured TiO2 particles on FTO conducting …

Enhanced catalysis based on the surface environment of the silica-supported metal complex

K Motokura, S Ding, K Usui, Y Kong - ACS Catalysis, 2021 - ACS Publications
Silica-supported metal complex catalysts have been developed and used for organic
transformations. The surface environment around the supported metal complex enhances …

The emergence of transition‐metal‐mediated hydrothiolation of unsaturated carbon–carbon bonds: a mechanistic outlook

R Castarlenas, A Di Giuseppe… - Angewandte Chemie …, 2013 - Wiley Online Library
The hydrothiolation of unsaturated carbon–carbon bonds is a practical and atom‐
economical approach for the incorporation of sulfur into organic frameworks. In recent years …

Recent advances in alkyne-based click polymerizations

D Huang, Y Liu, A Qin, BZ Tang - Polymer Chemistry, 2018 - pubs.rsc.org
Click chemistry, with remarkable advantages such as high efficiency, atom economy, mild
reaction conditions, very high yield, regio-and/or stereoselectivity, and good functionality …

Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts

A Di Giuseppe, R Castarlenas… - Journal of the …, 2012 - ACS Publications
Rh–N-heterocyclic carbene compounds [Rh (μ-Cl)(IPr)(η2-olefin)] 2 and RhCl (IPr)(py)(η2-
olefin)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-carbene, py= pyridine, olefin …

Externally stimulated click reactions for macromolecular syntheses

MA Tasdelen, B Kiskan, Y Yagci - Progress in Polymer Science, 2016 - Elsevier
Over the last decade, click chemistry reactions, that are fast, simple to use, easy to purify,
versatile, regiospecific, and give high product yields have gained significant importance for …

Regioselective hydrothiolation of alkynes by sulfonyl hydrazides using organic ionic base–Brønsted acid

R Singh, DS Raghuvanshi, KN Singh - Organic letters, 2013 - ACS Publications
A practical and novel approach has been developed for the synthesis of vinyl sulfides by the
reaction of sulfonyl hydrazides with aryl/heteroarylacetylenes using a DBU-based ionic …

Visible light initiated hydrothiolation of alkenes and alkynes over ZnIn 2 S 4

Y Li, J Cai, M Hao, Z Li - Green Chemistry, 2019 - pubs.rsc.org
The construction of C–S bonds is very important. The hydrothiolation of alkenes or alkynes
with thiols represents an attractive and atom economical approach for the formation of C–S …