Simulating coherent multidimensional spectroscopy of nonadiabatic molecular processes: From the infrared to the x-ray regime

M Kowalewski, BP Fingerhut, KE Dorfman… - Chemical …, 2017 - ACS Publications
Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …

Development of high harmonic generation spectroscopy of organic molecules and biomolecules

JP Marangos - Journal of Physics B: Atomic, Molecular and …, 2016 - iopscience.iop.org
In this review we will discuss the topic of high order harmonic generation (HHG) from
samples of organic and bio-molecules. The possibility to extract useful dynamical and …

[HTML][HTML] Non-adiabatic dynamics of molecules in optical cavities

M Kowalewski, K Bennett, S Mukamel - The Journal of chemical …, 2016 - pubs.aip.org
Strong coupling of molecules to the vacuum field of micro cavities can modify the potential
energy surfaces thereby opening new photophysical and photochemical reaction pathways …

Catching conical intersections in the act: Monitoring transient electronic coherences by attosecond stimulated X-ray Raman signals

M Kowalewski, K Bennett, KE Dorfman, S Mukamel - Physical review letters, 2015 - APS
Conical intersections (CIs) dominate the pathways and outcomes of virtually all
photophysical and photochemical molecular processes. Despite extensive experimental and …

Time-resolved photoelectron spectroscopy of conical intersections with attosecond pulse trains

D Jadoun, M Kowalewski - The Journal of Physical Chemistry …, 2021 - ACS Publications
Conical Intersections (CIs), which are believed to be ubiquitous in molecular and biological
systems, open up ultrafast nonradiative decay channels. A superposition of electronic states …

Accessing excited state molecular vibrations by femtosecond stimulated Raman spectroscopy

G Batignani, C Ferrante, T Scopigno - The Journal of Physical …, 2020 - ACS Publications
Excited state vibrations are crucial for determining the photophysical and photochemical
properties of molecular compounds. Stimulated Raman scattering can coherently stimulate …

Advances in instrumentation for FEL-based four-wave-mixing experiments

R Mincigrucci, L Foglia, D Naumenko… - Nuclear Instruments and …, 2018 - Elsevier
Experimental approaches based on nonlinear optical processes (wave-mixing) have
allowed major breakthroughs in diverse fields of science and technology. Nevertheless …

Nonadiabatic dynamics may be probed through electronic coherence in time-resolved photoelectron spectroscopy

K Bennett, M Kowalewski… - Journal of chemical theory …, 2016 - ACS Publications
We present a hierarchy of Fermi golden rules (FGRs) that incorporate strongly coupled
electronic/nuclear dynamics in time-resolved photoelectron spectroscopy (TRPES) signals …

Manipulating impulsive stimulated raman spectroscopy with a chirped probe pulse

L Monacelli, G Batignani, G Fumero… - The Journal of …, 2017 - ACS Publications
Photophysical and photochemical processes are often dominated by molecular vibrations in
various electronic states. Dissecting the corresponding, often overlapping, spectroscopic …

Tracking Conical Intersections with Nonlinear X-ray Raman Spectroscopy

D Jadoun, M Kowalewski - Ultrafast Science, 2022 - spj.science.org
Conical intersections are formed when 2 or more electronic states become degenerate and
give rise to ultrafast nonadiabatic processes such as radiation-less decay channels and …