Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media

K Asselman, C Kirschhock… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Since the discovery of synthetic zeolites in the 1940s and their implementation
in major industrial processes involving adsorption, catalytic conversion, and ion exchange …

[HTML][HTML] Facile synthesis of visible-responsive photocatalytic Eu-doped layered double hydroxide for selective removal of NOx pollutant

A Pastor, C Chen, G de Miguel, F Martín… - Chemical Engineering …, 2023 - Elsevier
Efficient nitrogen oxides (NO x) removal from the urban atmosphere is still a target for the
researchers. Herein, a Zn 2 Al-CO 3 based layered double hydroxide (LDH) was doped with …

Deep photocatalytic oxidation of aromatic VOCs on ZnSn LDH: promoting role of electron enrichment of surface hydroxyl

B Liu, Z Hu, B Zhang, B Liu, G Li, T Zhang, J Ji… - ACS …, 2023 - ACS Publications
Photocatalytic oxidation is a very promising technology for air purification, but its wide
application is greatly limited by poor mineralization capacity and catalytic stability. Herein …

Surface Hydroxyl and Oxygen Vacancies Engineering in ZnSnAl LDH: Synergistic Promotion of Photocatalytic Oxidation of Aromatic VOCs

B Liu, B Zhang, B Liu, Z Hu, W Dai… - Environmental …, 2024 - ACS Publications
Photocatalytic oxidation has gained great interest in environmental remediation, but it is still
limited by its low efficiency and catalytic deactivation in the degradation of aromatic VOCs. In …

[HTML][HTML] Harnessing nuclear magnetic resonance spectroscopy to decipher structure and dynamics of clathrate hydrates in confinement: a perspective

M Houlleberghs, S Radhakrishnan, CV Chandran… - Molecules, 2024 - mdpi.com
This perspective outlines recent developments in the field of NMR spectroscopy, enabling
new opportunities for in situ studies on bulk and confined clathrate hydrates. These hydrates …

Unravelling the effect of paramagnetic Ni 2+ on the 13 C NMR shift tensor for carbonate in Mg 2− x Ni x Al layered double hydroxides by quantum-chemical …

M Mohan, ABA Andersen, J Mareš… - Physical Chemistry …, 2023 - pubs.rsc.org
Structural disorder and low crystallinity render it challenging to characterise the atomic-level
structure of layered double hydroxides (LDH). We report a novel multi-step, first-principles …

Eu 3+ doped ZnAl layered double hydroxides as calibrationless, fluorescent sensors for carbonate

AF Morais, IGN Silva, BJ Ferreira, AC Teixeira… - Chemical …, 2023 - pubs.rsc.org
The photoluminescence properties (PL) of Eu3+ hosted in the hydroxide layers of layered
double hydroxides (LDHs) enables calibrationless quantification of anions in the interlayers …

Quadrupolar NMR crystallography guided crystal structure prediction (QNMRX-CSP)

AA Peach, CH Fleischer, K Levin, ST Holmes… - …, 2024 - pubs.rsc.org
We describe a new quadrupolar NMR crystallography guided crystal structure prediction
(QNMRX-CSP) protocol for the prediction and refinement of crystal structures, including its …

Polysilicate Porous Organic Polymers (PSiPOPs), a Family of Porous, Ordered 3D Reticular Materials with Polysilicate Nodes and Organic Linkers

J Jamoul, S Smet, S Radhakrishnan… - Chemistry of …, 2024 - ACS Publications
Spherosilicate, consisting of a double 4-ring cyclosilicate core (D4R; Si8O20) with every
corner functionalized with a dimethylsilyl chloride group (-SiMe2Cl), was used as a node to …

Improving Photoluminescence Emissions and Photostability of Dye/MgAl‐Layered Double Hydroxide Nanohybrids

Z Rezvani, L Jafari Foruzin, K Nejati - ChemistrySelect, 2023 - Wiley Online Library
The purpose of this study was the preparation of layered double hydroxide (LDH)‐based
nanohybrids with improved photoluminescence emission and high photostability. The anion …