Constrained geometry complexes—Synthesis and applications

H Braunschweig, FM Breitling - Coordination chemistry reviews, 2006 - Elsevier
Transition metal complexes bearing linked cyclopentadienyl amido ligands, regularly
referred to as constrained geometry complexes (CGCs), have found wide interest both in …

Organometallic catalysts for copolymerization of cyclic olefins

X Li, Z Hou - Coordination Chemistry Reviews, 2008 - Elsevier
This article provides an overview on recent progress in the addition copolymerization of
ethylene or α-olefins with cyclic olefins by various organometallic catalysts. Special …

Metallocene catalyzed ethene-and propene co-norbornene polymerization: Mechanisms from a detailed microstructural analysis

I Tritto, L Boggioni, DR Ferro - Coordination Chemistry Reviews, 2006 - Elsevier
Cyclic olefin copolymers are one of the new families of olefinic copolymers made available
by metallocenes. Owing to their unique combination of properties, they are engineered …

Nonbridged half-metallocenes containing anionic ancillary donor ligands: New promising candidates as catalysts for precise olefin polymerization

K Nomura, J Liu, S Padmanabhan… - Journal of Molecular …, 2007 - Elsevier
Recent examples for synthesis of group 4 transition metal (Ti, Zr, Hf) complexes, especially
nonbridged half-metallocenes containing anionic donor ligands of the type, Cp′ MX2 …

Propylene/cyclic olefin copolymers with cyclopentene, cyclohexene, cyclooctene, tricyclo [6.2. 1.0 (2, 7)] undeca-4-ene, and tetracyclododecene: the synthesis and …

M Okabe, K Nomura - Macromolecules, 2022 - ACS Publications
Propylene (P) copolymers with a series of cyclic olefins [cyclopentene (CPE), cyclohexene
(CHE), cis-cyclooctene (COE), tricyclo [6.2. 1.0 (2, 7)] undeca-4-ene (TCUE), and …

Living copolymerization of ethylene with norbornene catalyzed by bis (pyrrolide− imine) titanium complexes with MAO

Y Yoshida, J Mohri, S Ishii, M Mitani… - Journal of the …, 2004 - ACS Publications
Bis (pyrrolide− imine) Ti complexes in conjunction with methylalumoxane (MAO) were found
to work as efficient catalysts for the copolymerization of ethylene and norbornene to afford …

New titanium complexes with two β-enaminoketonato chelate ligands: Syntheses, structures, and olefin polymerization activities

XF Li, K Dai, WP Ye, L Pan, YS Li - Organometallics, 2004 - ACS Publications
New titanium complexes with two nonsymmetric bidentate β-enaminoketonato (N, O) ligands
(4a− e),[(Ph) NC (R2) C (H) C (R1) O] 2TiCl2, have been synthesized. X-ray crystal structure …

Stereoregular and stereoirregular alternating ethylene− norbornene copolymers

I Tritto, C Marestin, L Boggioni, MC Sacchi… - …, 2001 - ACS Publications
Ethylene− norbornene (E− N) copolymers were synthesized with the C 2 metallocene rac-
Me2Si (2-Me-[e]-benzindenyl) 2ZrCl2 (3) and with the constrained geometry Me2Si …

Half-titanocenes containing anionic ancillary donor ligands as promising new catalysts for precise olefin polymerisation

K Nomura - Dalton Transactions, 2009 - pubs.rsc.org
Recent efforts concerning nonbridged half-titanocenes containing anionic donor ligand of
the type, Cp′ TiX2 (Y)[Cp′= cyclopentadienyl group; X= halogen, alkyl; Y= anionic …

Copolymerization of ethene with norbornene derivatives using neutral nickel catalysts

GM Benedikt, E Elce, BL Goodall… - …, 2002 - ACS Publications
The copolymerization of ethene with norbornene derivatives, as well as their
terpolymerization with 1-alkenes, using a series of neutral, square-planar nickel complexes …