Theoretical Investigation of Single-Molecule-Magnet Behavior in Mononuclear Dysprosium and Californium Complexes

D Ray, MS Oakley, A Sarkar, X Bai… - Inorganic …, 2023 - ACS Publications
Early-actinide-based (U, Np, and Pu) single-molecule magnets (SMMs) have yet to show
magnetic properties similar to those of highly anisotropic lanthanide-based ones. However …

Pressure-induced spectroscopic changes in a californium 1D material are twice as large as found in the holmium analog

JM Sperling, E Warzecha, CJ Windorff… - Inorganic …, 2020 - ACS Publications
In this study, the synthesis, characterization, and pressure response of a 1D californium
mellitate (mellitate= 1, 2, 3, 4, 5, 6-benzenehexacarboxylate) coordination polymer, Cf2 …

Complex oxide nanoparticle synthesis: where to begin to do it right?

E Gager, W Halbert, JC Nino - Ceramics, 2022 - mdpi.com
Synthesis of advanced ceramics requires a high degree of control over the particle size and
stoichiometry of the material. When choosing a synthesis method for complex oxides it is …

Advancing understanding of actinide (iii)(Ac, Am, Cm) aqueous complexation chemistry

ZR Jones, MY Livshits, FD White, E Dalodière… - Chemical …, 2021 - pubs.rsc.org
The positive impact of having access to well-defined starting materials for applied actinide
technologies–and for technologies based on other elements–cannot be overstated. Of …

Radiolytic transformations of liquid hexafluoroacetylacetone

EM Kholodkova, AV Ponomarev - Radiation Physics and Chemistry, 2024 - Elsevier
Both at room temperature and at the boiling point, the formation of 10 primary molecular
products is recorded, whose concentration is directly proportional to the absorbed radiation …

Relativistic quantum calculations to understand the contribution of f-type atomic orbitals and chemical bonding of actinides with organic ligands

AD Zapata-Escobar, S Pakhira… - Physical Chemistry …, 2023 - pubs.rsc.org
The nuclear waste problem is one of the main interests of rare earth and actinide element
chemistry. Studies of actinide-containing compounds are at the frontier of the applications of …

Electronic Structure Calculations of Materials for Photovoltaic, Electrochemistry and Single Molecule Magnet Applications

D Ray - 2021 - search.proquest.com
One of the key scientific challenges of modern era is the efficient development of sustainable
energy sources. Towards this goal, efficient production of solar energy has garnered …

Relativistic Quantum Calculations to Understand the Contribution of f-Orbitals and Chemical Bonding of Actinides with Organic Ligands

AD Zapata-Escobar, S Pakhira… - arXiv preprint arXiv …, 2021 - arxiv.org
The nuclear waste problem is one of the main interests of the rare earth and actinide
elements chemistry. Studies of Actinide-containing compounds are at the frontier of the …

Quantum Chemical Treatment of Strongly Correlated Magnetic Systems Based on Heavy Elements. Final Report

L Gagliardi - 2022 - osti.gov
The objective of this project over the years has been to develop novel quantum chemical
methods and employ them to study the chemistry of systems containing actinides, and …

[图书][B] Optimizing Synthetic Conditions for the Stabilization of Divalent Californium

TN Poe - 2022 - search.proquest.com
In comparison to their lanthanide counterparts, the actinide elements are woefully
understudied. This is especially true for the trans-plutonium actinides. Known isotopes of the …