Carboxylate covalently modified polyoxometalates: From synthesis, structural diversity to applications

P Ma, F Hu, J Wang, J Niu - Coordination Chemistry Reviews, 2019 - Elsevier
Polyoxometalates (POMs) have demonstrated strong potential in various fields, such as
catalysis, magnetism, medicine, photochemistry and materials science, for their remarkable …

The bioinorganic chemistry of vanadium

D Rehder - Angewandte Chemie International Edition in …, 1991 - Wiley Online Library
Vanadium is a trace element that plays an important, perhaps essential and general role in
the regulation of enzymatic phosphorylations. Several forms of life, including the fly agaric …

Recent advances in poly (pyrazolyl) borate (scorpionate) chemistry

S Trofimenko - Chemical Reviews, 1993 - ACS Publications
Since their introduction in 1967, poly (pyrazolyl)-borates1 have found wide application in
coordination chemistry, and their complexes with most metals or metalloids of the periodic …

Coordination chemistry of vanadium in biological systems

A Butler, CJ Carrano - Coordination chemistry reviews, 1991 - Elsevier
In sharp contrast to most of the first row transition metal ions, the biochemistry of vanadium
has been relatively uninvestigated until recently. Sporadic reports dealing with the …

Spin exchange coupling in asymmetric heterodinuclear complexes containing the. mu.-oxo-bis (. mu.-acetato) dimetal core

R Hotzelmann, K Wieghardt, U Floerke… - Journal of the …, 1992 - ACS Publications
Synthesis of asymmetric heterodinuclear complexes [LM'(m-0)(m-CH3C02) 2M2L'] 2+,
where L represents 1, 4, 7-triazacyclononane, L'is 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane …

Novel scorpionate and pyrazole dioxovanadium complexes, catalysts for carboxylation and peroxidative oxidation of alkanes

TFS Silva, KV Luzyanin, MV Kirillova… - Advanced Synthesis …, 2010 - Wiley Online Library
The dioxovanadium (V) complexes [VO2 (3, 5‐Me2Hpz) 3][BF4](1)(pz= pyrazolyl),[VO2
{SO3C (pz) 3}](2),[VO2 {HB (3, 5‐Me2pz) 3}](3) and [VO2 {HC (pz) 3}][BF4](4), bearing …

Hydrolysis, Ligand Exchange, and Redox Properties of Vanadium Compounds: Implications of Solution Transformation on Biological, Therapeutic, and Environmental …

R Dinda, E Garribba, D Sanna, DC Crans… - Chemical …, 2025 - ACS Publications
Vanadium is a transition metal with important industrial, technological, biological, and
biomedical applications widespread in the environment and in living beings. The different …

A journey into the electrochemistry of vanadium compounds

P Galloni, V Conte, B Floris - Coordination Chemistry Reviews, 2015 - Elsevier
Vanadium is an element with a fascinating history, a widespread diffusion in bacteria and
eukaryan organisms, and rich coordination chemistry. The properties of vanadium …

Syntheses, electrochemistry, and spectroscopic and magnetic properties of new mononuclear and binuclear complexes of vanadium (III),-(IV, and-(V) containing the …

P Knopp, K Wieghardt, B Nuber, J Weiss… - Inorganic …, 1990 - ACS Publications
The reaction of LVCl3-dmf (1), where L represents the tridentate ligand 1, 4, 7-trimethyl-1, 4,
7-triazacyclononane (C9H21N3) and dmf is dimethylformamide, with CF3S03H yields the …

(. mu.-Hydroxo) bis (. mu.-carboxylato) diruthenium and (. mu.-oxo) bis (. mu.-carboxylato) diruthenium Complexes Containing Weatk Intramolecular Ru. cntdot.. cntdot …

P Neubold, K Wieghardt, B Nuber, J Weiss - Inorganic Chemistry, 1989 - ACS Publications
In recent years, the structural, electronic, and magnetic prop-erties of^-hydroxo^ isCg-
carboxylaU^ dimetal2" 6 complexes and their (g-oxo) bis^-carboxylato) dimetal7" 14 …