Peptides have been established as modular catalysts for various transformations. Still, the
vast number of potential amino acid building blocks renders the identification of peptides …

We report an enantio-and diastereodivergent synthesis of enantioenriched fluorenes
bearing bis-1, 3-nonadjacent stereocenters with broad substrate scope and high …

Solid-phase peptide synthesis (SPPS) is an essential technique for the synthesis of peptide.
For half a century, many amine detection methods have been developed to monitor coupling …

An efficient cascade 1, 6-addition/cyclization/enantioselective protonation pathway between
ene–yne–ketones and sodium sulfinates was realized. This protocol provides practical …

The construction of chiral motifs containing nonadjacent stereocenters in an enantio‐and
diastereoselective manner has long been a challenging task in synthetic chemistry …

Abstract Herein, a copper (I)‐catalyzed asymmetric 1, 4‐hydroarsination of β‐substituted α, β‐
unsaturated esters is achieved in moderate to excellent yields with high to excellent …

An enantioselective addition reaction for the construction of 1, 3‐nonadjacent stereogenic
centers is developed by means of a chiral strong Brønsted base catalyst. The chiral sodium …

A highly stereoselective protocol for the (3+ 2)-annulation of biphenyl-bridged seven-
membered cyclic N-sulfonylimines with γ-hydroxy-α, β-unsaturated ketones was developed …

The organocatalytic conjugate addition of aldehydes to β‐nitroacrylates provides direct
access to β‐ester‐γ‐nitroaldehydes and, thereby, common structural motifs of many …

A multi‐gram scale synthesis of ferrocenetriflone was optimised from ferrocenesulfonyl
fluoride and Me3SiCF3 (Ruppert reagent). Enantioselective deprotolithiations were then …