Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

LK Macreadie, KB Idrees, CS Smoljan… - Angewandte …, 2023 - Wiley Online Library
Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas,
which are acquiring rapid attention on an exponential basis. A significant characteristic of …

Effective approaches to boost Xe/Kr separation in Metal-Organic Frameworks: A review

JF Kurisingal, DW Kim, CS Hong - Coordination Chemistry Reviews, 2024 - Elsevier
Abstract Xenon (Xe) and krypton (Kr) separation is of great interest and plays an essential
role in the industry. However, the identical properties and ultra-low concentrations of Xe and …

Robust carborane-based metal–organic frameworks for hexane separation

KB Idrees, KO Kirlikovali, C Setter, H Xie… - Journal of the …, 2023 - ACS Publications
Hexane isomers play a vital role as feedstocks and fuel additives in the petrochemical
industry. However, their similar physical and chemical properties lead to significant …

Aperture Fine‐Tuning in Cage‐Like Metal–Organic Frameworks via Molecular Valve Strategy for Efficient Hexane Isomer Separation

R Chen, F Zheng, J Li, Y Liu, F Zhou, H Sun… - Small …, 2024 - Wiley Online Library
Cage‐like metal–organic frameworks (MOFs) are promising for hexane isomer separation,
but their aperture sizes are difficult to control precisely. Herein, a molecular valve strategy is …

Crystallographic and Compositional Dependence of Thermodynamic Stability of [Co (II), Cu (II), and Zn (II)] in 2-Methylimidazole-Containing Zeolitic Imidazolate …

GJ Leonel, CB Lennox, JM Marrett… - Chemistry of …, 2023 - ACS Publications
We report the first systematic study experimentally investigating the effect of changes to the
divalent metal node on the thermodynamic stability of three-dimensional (3D) and two …

[HTML][HTML] Synthesis and application of iron based metal organic framework for efficient adsorption of azo dyes from textile industry samples

K Goswami, M Ulaganambi, LK Sukumaran… - Advances in Sample …, 2023 - Elsevier
In this work, we have synthesized an iron based metal organic framework for removal of azo-
dyes from textile industry wastewaters. The metal organic framework is comprised of two …

Spontaneous resolution of two chiral metal–organic frameworks through local geometric and lattice frustration effects

HJ Windsor, CJ Kepert, LK Macreadie - CrystEngComm, 2023 - pubs.rsc.org
We highlight two key examples of where the achirality of reagents used in MOF syntheses
transposes to chiral structures, thereby expanding the potential ligand pool used in the …

Lab-scale insights into green metal-organic framework sorbents for gas separation or purification

AH Assen, K Adil, Y Belmabkhout - Current Opinion in Green and …, 2024 - Elsevier
Metal-organic frameworks (MOFs) have been proposed to provide solutions for industrially-
relevant gas separations due to their exciting structural and porosity attributes. Significant …

Efficient CO2 Capture and Separation in MOFs: Effect from Isoreticular Double Interpenetration

S Liu, L Wang, H Zhang, H Fang, X Yue… - … Applied Materials & …, 2024 - ACS Publications
Severe CO2 emissions has posed an increasingly alarming threat, motivating the
development of efficient CO2 capture materials, one of the key parts of carbon capture …

Thermally activated structural phase transitions and processes in metal–organic frameworks

C Castillo-Blas, AM Chester, DA Keen… - Chemical Society …, 2024 - pubs.rsc.org
The structural knowledge of metal–organic frameworks is crucial to the understanding and
development of new efficient materials for industrial implementation. This review classifies …