Recent years have witnessed rapid advances in the field of BN/CC isosterism, particularly in
the case of azaborinines. Examples of each isomer have now been synthesized and …

Abstract Replacement of C C unit with its isoelectronic B N unit in aromatics provides a
new class of molecules with appealing properties, which have attracted great attention …

Among aromatic compounds, borazarenes represent a significant class of isosteres in which
carbon‐carbon bonds have been replaced by B− N bonds. Described herein is a summary …

The first examples of biologically active monocyclic 1, 2‐azaborines have been synthesized
and demonstrated to exhibit not only improved in vitro aqueous solubility in comparison with …

A new catalytic synthetic route to functionalized 1, 2‐azaborinines has been developed by
the [2+ 2]/[2+ 4] cycloaddition reactions of di‐tert‐butyliminoboranes and alkynes in …

The first trans‐selective cyanoboration reaction of an alkyne, specifically a 1, 3‐enyne, is
described. The reported palladium‐catalyzed cyanoboration of 1, 3‐enynes is site‐, regio …

We report the first general synthesis of boron‐substituted monobenzofused 1, 4‐azaborines
using ring‐closing metathesis of an enamine‐containing diene as a key synthetic strategy …

Electronic and steric factors have been investigated in the thermal ring expansion of boroles
with organic azides, a reaction that provides access to highly arylated 1, 2‐azaborinines, BN …

Abstract The photochemistry of 1, 2‐dihydro‐1, 2‐azaborinine derivatives was studied under
matrix isolation conditions and in solution. Photoisomerization occurs exclusively to the …

We provide a seminal example of the utility of the 1, 2‐azaborine motif as a 4C+ 1N+ 1B
synthon in organic synthesis. Specifically, conditions for the practically scalable …