Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production

S Diyali, N Diyali, B Biswas - Coordination Chemistry Reviews, 2024 - Elsevier
Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Electrocatalytic hydrogen evolution with a copper porphyrin bearing meso-(o-carborane) substituents

X Peng, J Han, X Li, G Liu, Y Xu, Y Peng… - Chemical …, 2023 - pubs.rsc.org
A newly designed copper complex of 5, 15-bis (pentafluorophenyl)-10, 20-bis (o-carborane)
porphyrin (1) was synthesized and tested for the electrocatalytic hydrogen evolution reaction …

Exploring the multifarious role of the ligand in electrocatalytic hydrogen evolution reaction pathways

P Kumar, VP Tyagi, M Ghosh - Chemistry–A European Journal, 2023 - Wiley Online Library
In recent years, researchers have shifted their focus towards investigating the redox
properties of ancillary ligand backbones for small‐molecule activation. Several metal …

Directing Group Strategy for the Isolation of Organoselenium (VI) Benzoselenonates: Metal-Free Catalysts for Hydrogen Evolution Reaction

M Batabyal, S Jaiswal, RK Jha… - Journal of the American …, 2023 - ACS Publications
The exploration of fourth-period organoelements, particularly organoseleniums in their
highest VI oxidation state, is limited owing to their stability and synthesis. Herein, the …

Electrochemical CO2 Reduction Catalytic Activity and Materials Characterization of Heterogeneous Zinc Carbonaceous Layers Derived from a Zinc(II) Molecular …

F Nkurunziza, CA Phipps, DT Hofsommer… - ACS Applied Energy …, 2023 - ACS Publications
Homogeneous molecular electrocatalysts have shown promise as a highly tailorable
platform for designing active sites with high selectivity for target products. However, many …

Metal–Ligand Cooperativity Promotes Reversible Capture of Dilute CO2 as a Zn(II)-Methylcarbonate

CA Phipps, DT Hofsommer, CD Zirilli, BG Duff… - Inorganic …, 2023 - ACS Publications
In this study, a series of thiosemicarbazonato–hydrazinatopyridine metal complexes were
evaluated as CO2 capture agents. The complexes incorporate a non-coordinating, basic …

Palladium (II) pyridylidene sulfonamides (PYSAs) for electrocatalytic reduction of CO2

A Khurshid, MN Tahir, T Söhnel, EU Mughal… - Journal of Molecular …, 2025 - Elsevier
A new class of donor flexible nitrogen ligands, namely pyridylidene sulfonamides (PYSAs; N-
(1-benzylpyridin-4 (1H)-ylidene) benzene-sulfonamide, N-(1-benzylpyridin-4 (1H)-ylidene) …

Small organic molecular electrocatalysts for fuels production

C Torres‐Méndez, M Axelsson… - Angewandte Chemie …, 2024 - Wiley Online Library
In recent years, heterocyclic organic compounds have been explored as molecular
electrocatalysts in relevant reactions for energy conversion and storage. Merging mimetics …

Electrocatalytic Hydrogen Evolution using a Nickel‐based Calixpyrrole Complex: Controlling the Secondary Coordination Sphere on an Electrode Surface

L Trowbridge, B Averkiev… - Chemistry–A European …, 2023 - Wiley Online Library
Incorporating design elements from homogeneous catalysts to construct well defined active
sites on electrode surfaces is a promising approach for developing next generation …

The Hydrogen Evolution Reaction: Using Molecular Design in Transition Metal Complexes to Control Catalytic Microenvironments on Electrode Surfaces

L Trowbridge, PE Sues - ChemCatChem, 2024 - Wiley Online Library
Hydrogen gas and its production from renewable power sources will be an important part of
decreasing global reliance on fossil fuels and developing a sustainable energy economy …