Quantum-state controlled reaction channels in chemi-ionization processes: radiative (optical–physical) and exchange (oxidative–chemical) mechanisms

S Falcinelli, JM Farrar, F Vecchiocattivi… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus Most chemical processes are triggered by electron or charge transfer
phenomena (CT). An important class of processes involving CT are chemi-ionization …

The role of precursor states in the stereo-dynamics of elementary processes

S Falcinelli, D Cappelletti, F Vecchiocattivi… - Physical Chemistry …, 2023 - pubs.rsc.org
The present perspective review focuses on the role of the precursor state, controlling the
dynamical evolution of elementary processes, whose structure and stability are often difficult …

General treatment for stereo-dynamics of state-to-state chemi-ionization reactions

S Falcinelli, F Vecchiocattivi, F Pirani - Communications Chemistry, 2020 - nature.com
The investigation of chemi-ionization processes provides unique information on how the
reaction dynamics depend on the energy and structure of the transition state which relate to …

A new insight on stereo-dynamics of penning ionization reactions

S Falcinelli, F Pirani, P Candori, BG Brunetti… - Frontiers in …, 2019 - frontiersin.org
Recent developments in the experimental study of Penning ionization reactions are
presented here to cast light on basic aspects of the stereo-dynamics of the microscopic …

The stereodynamics of ion forming reactions

SDS Gordon, A Osterwalder - International Reviews in Physical …, 2020 - Taylor & Francis
Energy transfer reactions occur in all areas of chemistry. One fundamental form of this is
demonstrated by reactions in which an electronically excited atom transfers energy to a …

Symmetry Dependence of the Continuum Coupling in the Chemi-ionization of Li(22S1/2) by He(23S1, 23PJ)

T Sixt, T Chung, F Stienkemeier… - The Journal of Physical …, 2023 - ACS Publications
In the literature, the chemi-ionization of Li in the 22S1/2 ground level by He in a metastable
state is typically described as an electron transfer process in which an electron from the 2s …

Investigation of the low-energy stereodynamics in the Ne (3P2)+ N2, CO reactions

J Zou, A Osterwalder - The Journal of chemical physics, 2020 - pubs.aip.org
We report on an experimental investigation of the low-energy stereodynamics of the energy
transfer reactions Ne (3 P 2)+ X, producing Ne (1 S)+ X+ and [Ne–X]+(X= N 2 or CO) …

Energy transfer and spin changing in collisions of Rydberg atoms with ground-state molecules at~ 1 K

K Gawlas - 2022 - discovery.ucl.ac.uk
The resonant energy transfer process between Rydberg He atoms, with n values near 40,
and ground-state NH3 molecules has been investigated experimentally at collision …

[PDF][PDF] Spectroscopic and atom-optics experiments on Rydberg He in electric and magnetic fields: towards low-temperature investigations of ion-molecule chemistry …

M Žeško - 2019 - research-collection.ethz.ch
Please allow me to preface this volume with expressions of gratitude to the many people
who have made this thesis possible through their direct or indirect support. While I strive to …

Low-energy stereodynamics of ion-forming reactions

J Zou - 2021 - infoscience.epfl.ch
In this thesis, an experimental study of low-temperature stereodynamics in the reactive
scattering of Ne (3P2)+ X collisions (X= Ar, Kr, Xe, CO and N2) is presented. The steric effect …