Surfactants produced from carbohydrate derivatives: A review of the biobased building blocks used in their synthesis

MS Ortiz, JG Alvarado, F Zambrano… - Journal of Surfactants …, 2022 - Wiley Online Library
This work reviews the use of carbohydrates and their derivatives as renewable raw materials
in the production of surfactants. Methods to attain state‐of‐the‐art carbohydrate‐derived …

Toward renewable amines: recent advances in the catalytic amination of biomass-derived oxygenates

NK Gupta, P Reif, P Palenicek, M Rose - ACS Catalysis, 2022 - ACS Publications
Synthesis of high-value-added chemicals from biomass and/or biomass-derived platform
molecules is considered an important strategy to mitigate the global dependency on fossil …

Sustainable valorisation of renewables through dialkyl carbonates and isopropenyl esters

G Fiorani, A Perosa, M Selva - Green Chemistry, 2023 - pubs.rsc.org
This review showcases a thorough analysis of reactions and applications of the most
widespread linear and alkylene organic carbonates (DACs), dimethyl-, diethyl-, ethylene …

Digital Light Processing 3D Printing of Isosorbide-and Vanillin-Based Ester and Ester–Imine Thermosets: Structure–Property Recyclability Relationships

A Liguori, E Oliva, M Sangermano… - ACS Sustainable …, 2023 - ACS Publications
Four isosorbide-based photocurable resins were designed to reveal correlations between
the composition and chemical structure, digital light processing (DLP) three-dimensional …

Eugenol-DOPO: a bio-based phosphorous-containing monomer for thiol-ene photocurable thermosets

O Ozukanar, E Çakmakçi, G Sagdic, US Gunay… - Journal of Polymers and …, 2023 - Springer
The adverse health and environmental effects of petroleum-based materials have become a
driving force for the fabrication of bio-based monomers. In this study, we synthesized a novel …

Fully renewable photocrosslinkable polycarbonates from cellulose-derived monomers

S Fadlallah, A Kayishaer, M Annatelli… - Green …, 2022 - pubs.rsc.org
Cellulose-derived photocrosslinkable polycarbonates (PCs) with renewable citronellol
pendant chains were synthesised through the polycondensation of Triol-citro, a recently …

Fully biobased UV-cured thiol-ene coatings

L Pezzana, M Sangermano - Progress in Organic Coatings, 2021 - Elsevier
New fully biobased formulation was developed and UV cured to obtain a polymer network
useful for coating applications. Lipoic acid and isosorbide diallyl were used as functional …

Cationic UV-curing of isosorbide-based epoxy coating reinforced with macadamia nut shell powder

L Pezzana, A Emanuele, R Sesana, C Delprete… - Progress in Organic …, 2023 - Elsevier
The scientific community is deeply investigating bio-based derivatives to reduce the
consumption of fossil-based material and lessen the environmental impact. The …

Helical crystals in aliphatic copolyesters: From chiral amplification to mechanical property enhancement

J Li, S Wang, H Lu, Y Tu, X Wan, X Li, Y Tu… - ACS macro …, 2023 - ACS Publications
We demonstrate herein a bottom-up strategy for achieving helical crystals via chiral
amplification in copolyesters by incorporating a small amount of (d)-isosorbide into …

Efficient synthesis of bio-derived polycarbonates from dimethyl carbonate and isosorbide: regulating exo-OH and endo-OH reactivity by ionic liquids

W Qian, X Ma, L Liu, L Deng, Q Su, R Bai, Z Zhang… - Green …, 2020 - pubs.rsc.org
It is an immense challenge to design catalysts for synthesizing high molecular weight
polycarbonates using CO2, CO2-based compounds, or biorenewable chemicals as building …