Roles of water for chemical reactions in high-temperature water
N Akiya, PE Savage - Chemical reviews, 2002 - ACS Publications
High-temperature water (HTW), which we define broadly herein as liquid water above 200 C
and supercritical water (T> 374 C, P> 218 atm), is attracting attention as a medium for …
and supercritical water (T> 374 C, P> 218 atm), is attracting attention as a medium for …
On the Molecular-Based Thermodynamics of Dilute Solutions Along Orthobaric Conditions Concise review of the fundamental microscopic constraints, rigorous formal …
AA Chialvo, OD Crisalle - Journal of Molecular Liquids, 2023 - Elsevier
We review the fundamentals underlying a rigorous and general molecular-based formalism
for the microscopic interpretation of the solvation phenomena involving dilute solutes along …
for the microscopic interpretation of the solvation phenomena involving dilute solutes along …
Preferential solvation in pharmaceutical processing: Rigorous results, critical observations, and the unraveling of some significant modeling pitfalls
AA Chialvo - Fluid Phase Equilibria, 2025 - Elsevier
We probe the solvent effects on the preferential solvation of pharmaceutical species in
mixed-solvent environments, identify its universal molecular-based signature, and …
mixed-solvent environments, identify its universal molecular-based signature, and …
[PDF][PDF] Molecular‐based modeling of water and aqueous solutions at supercritical conditions
AA Chialvo, PT Cummings - Advances in Chemical Physics, 1999 - researchgate.net
Molecular-Based Modeling of Water and Aqueous Solutions at Supercritical Conditions Page 1
MOLECULAR-BASED MODELING OF WATER AND AQUEOUS SOLUTIONS AT SUPERCRITICAL …
MOLECULAR-BASED MODELING OF WATER AND AQUEOUS SOLUTIONS AT SUPERCRITICAL …
Densities and Excess, Apparent, and Partial Molar Volumes of Binary Mixtures of BMIMBF4 + Ethanol as a Function of Temperature, Pressure, and Concentration
The densities of five BMIMBF 4 (1-butyl-3-methylimidazolium tetrafluoroborate)+ ethanol
binary mixtures with compositions of (0.0701, 0.3147, 0.5384, 0.7452, and 0.9152) mole …
binary mixtures with compositions of (0.0701, 0.3147, 0.5384, 0.7452, and 0.9152) mole …
Liquid−Liquid−Vapor, Liquid−Liquid, and Liquid−Vapor Phase Transitions in Aqueous n-Hexane Mixtures from Isochoric Heat Capacity Measurements
IK Kamilov, GV Stepanov, IM Abdulagatov… - Journal of Chemical & …, 2001 - ACS Publications
The constant volume and constant composition heat capacity C VX data for aqueous n-
hexane mixtures are reported for seven compositions,(0.6146, 0.7965, 0.9349, 0.9775 …
hexane mixtures are reported for seven compositions,(0.6146, 0.7965, 0.9349, 0.9775 …
On the solvation thermodynamics involving species with large intermolecular asymmetries: a rigorous molecular-based approach to simple systems with …
AA Chialvo - The Journal of Physical Chemistry B, 2020 - ACS Publications
This work deals with the solvation thermodynamics of systems containing extreme
intermolecular interaction asymmetries, such as binary mixtures comprising ideal gas …
intermolecular interaction asymmetries, such as binary mixtures comprising ideal gas …
Membrane reactor for homogeneous catalysis in supercritical carbon dioxide
ELV Goetheer, AW Verkerk, LJP Van Den Broeke… - Journal of …, 2003 - Elsevier
A membrane reactor is presented for homogeneous catalysis in supercritical carbon dioxide
with in situ catalyst separation. This concept offers the advantages of benign high-density …
with in situ catalyst separation. This concept offers the advantages of benign high-density …
Why do co‐solvents enhance the solubility of solutes in supercritical fluids? New evidence and opinion
X Zhang, B Han, Z Hou, J Zhang, Z Liu… - … A European Journal, 2002 - Wiley Online Library
The effects of two polar co‐solvents, chlorodifluoromethane and acetone, on the solubility
and enthalpy of a solution of 1, 4‐naphthoquinone in supercritical (SC) CO2 were studied …
and enthalpy of a solution of 1, 4‐naphthoquinone in supercritical (SC) CO2 were studied …
Solvent and H/D isotopic substitution effects on the Krichevskii parameter of solutes: a novel approach to their accurate determination
AA Chialvo, OD Crisalle - Liquids, 2022 - mdpi.com
We establish a direct route for the accurate determination of the solvent effect on the
Krichevskii parameter of a solute, based solely on the contrasting solvation behavior of the …
Krichevskii parameter of a solute, based solely on the contrasting solvation behavior of the …