Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formations have been
made with nickel-catalyzed cross-coupling of racemic alkyl electrophiles with organometallic …

In contrast to the extensive but non-recyclable use of tetraalkoxydiboron (4) compounds as
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …

Herein, we disclose a Ni-catalyzed 1, 1-difunctionalization of unactivated terminal alkenes
that enables the incorporation of two different heteroatom motifs across an olefin backbone …

Deoxygenative difunctionalization of carbonyls affords a straightforward and effective route
to construct geminal dual functionalized motifs. However, the research in this field is very …

Bis‐boronic esters are useful synthetic intermediates particularly as the two boronic esters
can be selectively functionalized. Usually, the less hindered primary boronic ester reacts, but …

gem-Difluoroalkenyl boronates are attractive synthons for constructing diverse gem-
difluoroalkenes and organoboron compounds. However, the strategies for the construction …

To meet the need for a rapid, streamlined, and potentially automatable molecule synthesis,
modular coupling approaches are highly desired. While the diversification of aromatic …

Owing to its simplicity, ethylene, as the most abundant organic feedstock, only finds limited
applications in fine chemical synthesis, resulting in molecules of modest complexity …