Formation of complex organic molecules in hot molecular cores through nondiffusive grain-surface and ice-mantle chemistry

RT Garrod, M Jin, KA Matis, D Jones… - The Astrophysical …, 2022 - iopscience.iop.org
A new, more comprehensive model of gas–grain chemistry in hot molecular cores is
presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice …

Astrochemical pathways to complex organic and prebiotic molecules: Experimental perspectives for in situ solid-state studies

D Fulvio, A Potapov, J He, T Henning - Life, 2021 - mdpi.com
A deep understanding of the origin of life requires the physical, chemical, and biological
study of prebiotic systems and the comprehension of the mechanisms underlying their …

Efficient production of S8 in interstellar ices: The effects of cosmic-ray-driven radiation chemistry and nondiffusive bulk reactions

CN Shingledecker, T Lamberts, JC Laas… - The Astrophysical …, 2020 - iopscience.iop.org
In this work, we reexamine sulfur chemistry occurring on and in the ice mantles of interstellar
dust grains, and report the effects of two new modifications to standard astrochemical …

A Revised Description of the Cosmic Ray Induced Desorption of Interstellar Ices

O Sipilä, K Silsbee, P Caselli - The Astrophysical Journal, 2021 - iopscience.iop.org
Nonthermal desorption of ices on interstellar grains is required to explain observations of
molecules that are not synthesized efficiently in the gas phase in cold dense clouds …

Evidence of surface catalytic effect on cosmic dust grain analogs: The ammonia and carbon dioxide surface reaction

A Potapov, P Theulé, C Jäger… - The Astrophysical …, 2019 - iopscience.iop.org
Surface chemistry on cosmic dust grains plays an important role in the formation of
molecules at low temperatures in the interstellar and circumstellar environments. For the first …

On simulating the proton-irradiation of O2 and H2o ices using astrochemical-type models, with implications for bulk reactivity

CN Shingledecker, A Vasyunin, E Herbst… - The Astrophysical …, 2019 - iopscience.iop.org
Many current astrochemical models explicitly consider the species that comprise the bulk of
interstellar dust grain ice mantles separately from those in the top few monolayers …

The effect of cosmic rays on cometary nuclei. ii. impact on ice composition and structure

R Maggiolo, G Gronoff, G Cessateur… - The Astrophysical …, 2020 - iopscience.iop.org
Since their formation in the protosolar nebula some∼ 4.5 billion years ago, comets are in
storage in cold distant regions of the solar system, the Kuiper Belt/scattered disk or Oort …

Influence of ice structure on the soft UV photochemistry of PAHs embedded in solid water

JA Noble, E Michoulier, C Aupetit, J Mascetti - Astronomy & Astrophysics, 2020 - aanda.org
Context. The UV photoreactivity of polycyclic aromatic hydrocarbons (PAHs) in porous
amorphous solid water has long been known to form both oxygenated photoproducts and …

Formation of CO2 Driven by Photochemistry of Water Ice Mixed with Carbon Grains

A Potapov, D Semenov, C Jäger… - The Astrophysical …, 2023 - iopscience.iop.org
We present results on photochemistry of carbon-grains/water-ice mixtures at temperatures
from 10 to 150 K. Such a temperature range corresponds to the physical conditions found in …

A novel framework for studying the impact of binding energy distributions on the chemistry of dust grains

T Grassi, S Bovino, P Caselli, G Bovolenta… - Astronomy & …, 2020 - aanda.org
The evaporation of molecules from dust grains is crucial to understanding some key aspects
of the star-and the planet-formation processes. During the heating phase, the presence of …