Naphthopyran molecular switches and their emergent mechanochemical reactivity

ME McFadden, RW Barber, AC Overholts… - Chemical Science, 2023 - pubs.rsc.org
Naphthopyran molecular switches undergo a ring-opening reaction upon external
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …

Technology pull: scale-up of polymeric mechanochemical force sensors

N Willis-Fox, E Watchorn-Rokutan, E Rognin, R Daly - Trends in Chemistry, 2023 - cell.com
Polymer mechanochemistry uses mechanical forces to break and manipulate chemical
bonds, driving a functional response in the material of choice, thus making it an ideal …

Bio‐inspired structure‐editing fluorescent hydrogel actuators for environment‐interactive information encryption

R Wang, Y Zhang, W Lu, B Wu, S Wei… - Angewandte Chemie …, 2023 - Wiley Online Library
Many living organisms have the superb structure‐editing capacity for better adaptation in
dynamic environments over the course of their life cycle. However, it's still challenging to …

Mechanochemical Release of Fluorophores from a “Flex‐activated” Mechanophore

F Yang, T Geng, H Shen, Y Kou, G Xiao… - Angewandte Chemie …, 2023 - Wiley Online Library
Optical force probes that can release force‐dependent and visualized signals with minimal
changes in the polymer main chains under mechanical load are highly sought after but …

Multicolor chromism from a single chromophore through synergistic coupling of mechanochromic and photochromic subunits

W He, Y Yuan, M Wu, X Li, Y Shen, Z Qu… - Angewandte …, 2023 - Wiley Online Library
We report a versatile mechanophore exhibiting a vividly detectable, light‐regulable
multicolor mechanochromism. Such optical features rely on the synergistic coupling of …

Coumarin Dimer Is an Effective Photomechanochemical AND Gate for Small-Molecule Release

X He, Y Tian, RT O'Neill, Y Xu, Y Lin… - Journal of the …, 2023 - ACS Publications
Stimulus-responsive gating of chemical reactions is of considerable practical and
conceptual interest. For example, photocleavable protective groups and gating …

Thermally stable photomechanical molecular hinge: Sterically hindered stiff-stilbene photoswitch mechanically isomerizes

K Imato, A Ishii, N Kaneda, T Hidaka, A Sasaki, I Imae… - JACS Au, 2023 - ACS Publications
Molecular photoswitches are extensively used as molecular machines because of the small
structures, simple motions, and advantages of light including high spatiotemporal resolution …

Furan release via force-promoted retro-[4+ 2][3+ 2] cycloaddition

K Suwada, AW Ieong, HLH Lo… - Journal of the American …, 2023 - ACS Publications
Mechanophores (mechanosensitive molecules) have been instrumental in the development
of various force-controlled release systems. However, the release of functional organic …

Anomalous photochromism and mechanochromism of a linear naphthopyran enabled by a polarizing dialkylamine substituent

Y Sun, ME McFadden, SK Osler, RW Barber… - Chemical …, 2023 - pubs.rsc.org
In contrast to common angular naphthopyrans that exhibit strong photochromic and
mechanochromic behavior, constitutionally isomeric linear naphthopyrans are typically not …

Xanthene-based functional dyes: Towards new molecules operating in the near-infrared region

S Kamino, M Uchiyama - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Xanthene-based functional dyes have diverse applications in life science and materials
science. A current challenge is to develop new dyes with suitable physicochemical …