Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Metal–organic framework-based enzyme biocomposites

W Liang, P Wied, F Carraro, CJ Sumby… - Chemical …, 2021 - ACS Publications
Because of their efficiency, selectivity, and environmental sustainability, there are significant
opportunities for enzymes in chemical synthesis and biotechnology. However, as the three …

A historical overview of the activation and porosity of metal–organic frameworks

X Zhang, Z Chen, X Liu, SL Hanna, X Wang… - Chemical Society …, 2020 - pubs.rsc.org
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …

Nanozymes: classification, catalytic mechanisms, activity regulation, and applications

Y Huang, J Ren, X Qu - Chemical reviews, 2019 - ACS Publications
Because of the high catalytic activities and substrate specificity, natural enzymes have been
widely used in industrial, medical, and biological fields, etc. Although promising, they often …

Metal-organic frameworks as novel matrices for efficient enzyme immobilization: an update review

S Liang, XL Wu, J Xiong, MH Zong, WY Lou - Coordination Chemistry …, 2020 - Elsevier
As a typical green methodology, enzymatic catalysis has been extensively employed in
multitudinous chemical and biological transformation procedures. However, intrinsic fragile …

Metal–organic‐framework‐engineered enzyme‐mimetic catalysts

L Ma, F Jiang, X Fan, L Wang, C He, M Zhou… - Advanced …, 2020 - Wiley Online Library
Nanomaterial‐based enzyme‐mimetic catalysts (Enz‐Cats) have received considerable
attention because of their optimized and enhanced catalytic performances and selectivities …

Biocatalytic cascades driven by enzymes encapsulated in metal–organic framework nanoparticles

WH Chen, M Vázquez-González, A Zoabi… - Nature Catalysis, 2018 - nature.com
Biocatalytic transformations in cells, such as enzyme cascades, involve complex networks
proceeding in spatially confined microenvironments. Here, inspired by nature, we …

Metal–organic frameworks based on multicarboxylate linkers

H Ghasempour, KY Wang, JA Powell… - Coordination Chemistry …, 2021 - Elsevier
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

Enzyme–MOF (metal–organic framework) composites

X Lian, Y Fang, E Joseph, Q Wang, J Li… - Chemical Society …, 2017 - pubs.rsc.org
The ex vivo application of enzymes in various processes, especially via enzyme
immobilization techniques, has been extensively studied in recent years in order to enhance …