There has been intense interest during recent years in identifying the biological functions of
carbohydrates. This diverse class of biomolecule is now well recognized as playing …

The selectins are a family of cell‐adhesion proteins that mediate the rolling of leukocytes on
activated endothelial cells through the recognition of the carbohydrate epitope sialyl Lewisx …

Spirocyclic C‐arylglycosides were synthesized from the appropriately protected δ‐
gluconolactones. Addition of lithium acetylide followed by glycosylation with 3‐(trimethylsilyl) …

Abstract Design of multivalent glycoconjugates can find applications such as in anti-
adhesive therapy against bacterial infections. Nevertheless, the access to such …

The excitation of the innermost carbonyl of nono‐2, 3‐diulose derivatives by irradiation with
visible‐light initiates a sequential Norrish type II photoelimination and aldol cyclization …

Palladium-catalyzed oxidation of benzylated aldose hemiacetals to lactones - ScienceDirect Skip
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Fully protected triphenylmethyl 2-O-mesyl-1-thio-β-d-gluco-(14) and-α-d-mannopyranoside
(28) were transformed by a stereoselective intramolecular 1→ 2 trans-arylthio migration into …

The first synthesis of the sulfonate analogue of seminolipid, the main sulfoglycolipid in
mammalian sperm, is reported. Installation of the sulfonate unit was accomplished by a quite …

Efficient methods for functionalization of readily available exo‐glycals have been developed.
Sequential palladium‐catalysed cross‐coupling of dibromo‐substituted exo‐glycals was first …

The 4-O-sulfuric esters of methyl 6-deoxy-α-L-talo-and-α-L-mannopyranoside were
prepared. The first ester is a component of the glycopeptidolipid-type cell surface antigens of …