The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Background: Cancer is a foremost cause of mortality worldwide. Available treatments are
non-specific and cannot cross biological barriers, which have restricted their usages …

Organophosphorus zwitterions are one of the most important but elusive intermediates for
carbon–carbon bond formation in synthetic chemistry and biology. However, a lack of …

Radical reaction of [60] fullerene with phosphonates or phosphine oxide mediated by
manganese (III) acetate dihydrate in chlorobenzene under three different conditions afforded …

Manganese(iii) acetate -mediated radical reaction of [60]fullerene with phosphonate esters
affording unprecedented separable singly-bonded [60]fuller ... - Chemical Communications (RSC …

The CuCl2-mediated three-component reaction of C60 with amines and dimethyl
acetylenedicarboxylate afforded the fulleropyrrolines in moderate yields. Furthermore, the …

Three-Component and Nonclassical Reaction of Phosphines with Enynes and Aldehydes:
Formation of γ-Lactones Featuring α-Phosphorus Ylides | Organic Letters ACS ACS …

Phosphine-promoted unprecedented [3+ 2] annulation reactions via ring expansion by using
2-benzylidene-indane-1, 3-diones and diynoates for the synthesis of biologically interesting …

Organophosphines are versatile Lewis basic catalysts that have been confirmed as powerful
tools in organic synthesis for the past two decades. The nucleophilic addition of …

Herein we demonstrate a tricyclohexylphosphine‐catalyzed cycloaddition of (E)‐or (Z)‐alkyl
5‐substituted phenylpent‐2‐en‐4‐ynoates with [60] fullerene to give cyclopentenofullerenes …