Combustion, chemistry, and carbon neutrality

K Kohse-Höinghaus - Chemical Reviews, 2023 - ACS Publications
Combustion is a reactive oxidation process that releases energy bound in chemical
compounds used as fuels─ energy that is needed for power generation, transportation …

First-generation organic reaction intermediates in zeolite chemistry and catalysis

X Gong, M Caglayan, Y Ye, K Liu, J Gascon… - Chemical …, 2022 - ACS Publications
Zeolite chemistry and catalysis are expected to play a decisive role in the next decade (s) to
build a more decentralized renewable feedstock-dependent sustainable society owing to the …

Evaluating the role of descriptor-and spectator-type reaction intermediates during the early phases of zeolite catalysis

X Gong, Y Ye, AD Chowdhury - ACS Catalysis, 2022 - ACS Publications
The philosophy of “Ikigai”─ a reason for being─ could be extended to rationalize the role of
organic reaction intermediates in zeolite catalysis. Each reaction intermediate's ikigai is …

Continuous pyrolysis microreactors: Hot sources with little cooling? New insights utilizing cation velocity map imaging and threshold photoelectron spectroscopy

P Hemberger, X Wu, Z Pan, A Bodi - The Journal of Physical …, 2022 - ACS Publications
Resistively heated silicon carbide microreactors are widely applied as continuous sources to
selectively prepare elusive and reactive intermediates with astrochemical, catalytic, or …

Gas phase synthesis of the C40 nano bowl C40H10

LB Tuli, SJ Goettl, AM Turner, AH Howlader… - Nature …, 2023 - nature.com
Nanobowls represent vital molecular building blocks of end-capped nanotubes and
fullerenes detected in combustion systems and in deep space such as toward the planetary …

Photoion Mass-Selected Threshold Photoelectron Spectroscopy to Detect Reactive Intermediates in Catalysis: From Instrumentation and Examples to Peculiarities …

P Hemberger, Z Pan, X Wu, Z Zhang… - The Journal of …, 2023 - ACS Publications
Photoion mass-selected threshold photoelectron spectroscopy (ms-TPES) is a synchrotron-
based, universal, sensitive, and multiplexed detection tool applied in the areas of catalysis …

Photodissociation and photoionization of molecules of astronomical interest-Updates to the Leiden photodissociation and photoionization cross section database

HR Hrodmarsson, EF Van Dishoeck - Astronomy & Astrophysics, 2023 - aanda.org
Context. Vacuum-ultraviolet (VUV) photons are important drivers of chemical processes in
space. Thus, it is important to accurately characterize and constrain photorates in different …

Photoelectron spectroscopy in molecular physical chemistry

I Fischer, ST Pratt - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Photoelectron spectroscopy has long been a powerful method in the toolbox of experimental
physical chemistry and molecular physics. Recent improvements in coincidence methods …

A solution for 4-propylguaiacol hydrodeoxygenation without ring saturation

Z Zhang, Q Li, X Wu, C Bourmaud, DG Vlachos… - Nature …, 2024 - nature.com
We investigate solvent effects in the hydrodeoxygenation of 4-propylguaiacol (4PG, 166
amu), a key lignin-derived monomer, over Ru/C catalyst by combined operando synchrotron …

Gas-phase synthesis of coronene through stepwise directed ring annulation

SJ Goettl, LB Tuli, AM Turner, Y Reyes… - Journal of the …, 2023 - ACS Publications
Molecular beam experiments together with electronic structure calculations provide the first
evidence of a complex network of elementary gas-phase reactions culminating in the bottom …