Visible-to-NIR-light activated release: from small molecules to nanomaterials
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …
Photoactive ruthenium nitrosyls as NO donors: how to sensitize them toward visible light
NL Fry, PK Mascharak - Accounts of chemical research, 2011 - ACS Publications
Nitric oxide (NO) can induce apoptosis (programmed cell death) at micromolar or higher
doses. Although cell death via NO-induced apoptosis has been studied quite extensively …
doses. Although cell death via NO-induced apoptosis has been studied quite extensively …
Photoactive ruthenium nitrosyls: Effects of light and potential application as NO donors
MJ Rose, PK Mascharak - Coordination chemistry reviews, 2008 - Elsevier
In recent years, various exogenous nitric oxide (NO) donors have been synthesized to
modulate NO concentrations in cellular environments and control physiological processes …
modulate NO concentrations in cellular environments and control physiological processes …
Polychromophoric metal complexes for generating the bioregulatory agent nitric oxide by single-and two-photon excitation
PC Ford - Accounts of chemical research, 2008 - ACS Publications
In order to deliver a bioactive agent to a physiological location, it is important to be able to
regulate precisely the location and the dosage. Such exquisite control can easily be …
regulate precisely the location and the dosage. Such exquisite control can easily be …
New features in the redox coordination chemistry of metal nitrosyls {M–NO+; M–NO; M–NO−(HNO)}
We describe new developments in the coordination chemistry of bound nitrosyl, considering
its three formal redox states: NO+, NO and NO−/HNO. We emphasize on the correlation …
its three formal redox states: NO+, NO and NO−/HNO. We emphasize on the correlation …
Structural, Spectroscopic, and Computational Study of an Octahedral, Non-Heme {Fe−NO}6-8 Series: [Fe(NO)(cyclam-ac)]2+/+/0
RG Serres, CA Grapperhaus, E Bothe… - Journal of the …, 2004 - ACS Publications
The reaction of low-spin [FeIICl (cyclam-ac)] with NO in CH3CN yields the octahedral, non-
heme (nitrosyl) iron complex [Fe (NO)(cyclam-ac)](PF6)(2), S= 1/2, which can be one …
heme (nitrosyl) iron complex [Fe (NO)(cyclam-ac)](PF6)(2), S= 1/2, which can be one …
Sensitization of ruthenium nitrosyls to visible light via direct coordination of the dye resorufin: trackable NO donors for light-triggered NO delivery to cellular targets
MJ Rose, NL Fry, R Marlow, L Hinck… - Journal of the …, 2008 - ACS Publications
Three nitrosyl-dye conjugates, namely,[(Me2bpb) Ru (NO)(Resf)](1-Resf),[(Me2bQb) Ru
(NO)(Resf)](2-Resf), and [((OMe) 2bQb) Ru (NO)(Resf)](3-Resf) have been synthesized via …
(NO)(Resf)](2-Resf), and [((OMe) 2bQb) Ru (NO)(Resf)](3-Resf) have been synthesized via …
Local Oxidation States in {FeNO}6–8 Porphyrins: Insights from DMRG/CASSCF–CASPT2 Calculations
A first DMRG/CASSCF–CASPT2 study of a series of paradigmatic {FeNO} 6,{FeNO} 7, and
{FeNO} 8 heme–nitrosyl complexes has led to substantial new insight as well as uncovered …
{FeNO} 8 heme–nitrosyl complexes has led to substantial new insight as well as uncovered …
Near-infrared light activated release of nitric oxide from designed photoactive manganese nitrosyls: strategy, design, and potential as NO donors
AA Eroy-Reveles, Y Leung, CM Beavers… - Journal of the …, 2008 - ACS Publications
Two new manganese complexes derived from the pentadentate ligand N, N-bis (2-
pyridylmethyl) amine-N-ethyl-2-quinoline-2-carboxamide, PaPy2QH, where H is dissociable …
pyridylmethyl) amine-N-ethyl-2-quinoline-2-carboxamide, PaPy2QH, where H is dissociable …
Near-IR light-induced photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes: formation, reactivity, and biological effects
Polypyridyl backbone nitrosyl complexes of ruthenium with the molecular framework [RuII
(antpy)(bpy) NO+/˙] n+ [4](PF6) 3 (n= 3),[4](PF6) 2 (n= 2), where antpy= 4′-(anthracene-9 …
(antpy)(bpy) NO+/˙] n+ [4](PF6) 3 (n= 3),[4](PF6) 2 (n= 2), where antpy= 4′-(anthracene-9 …