Mechanisms responsible for chemical shifts of core-level binding energies and their relationship to chemical bonding

PS Bagus, F Illas, G Pacchioni, F Parmigiani - Journal of electron …, 1999 - Elsevier
A comprehensive review of different mechanisms which contribute to the chemical shifts of
core-level binding energies, BEs, is made. A principle focus is on showing how the …

Current progress in understanding alkali metal adsorption on metal surfaces

RD Diehl, R McGrath - Journal of Physics: Condensed Matter, 1997 - iopscience.iop.org
This paper reviews the current situation in the understanding of alkali adsorption on metal
surfaces, with particular emphasis on recent structural discoveries. We start by describing …

Adsorbate-substrate and adsorbate-adsorbate interactions of Na and K adlayers on Al (111)

J Neugebauer, M Scheffler - Physical Review B, 1992 - APS
We present total-energy, force, and electronic-structure calculations for Na and K adsorbed
in various geometries on an Al (111) surface. The calculations apply density-functional …

Surface core-level shifts of clean and oxygen-covered Ru (0001)

S Lizzit, A Baraldi, A Groso, K Reuter… - Physical Review B, 2001 - APS
We have performed high resolution x-ray photoemission spectroscopy experiments on the
Ru (0001) surface, both clean and covered with well-defined amounts of oxygen up to 1 …

Geometric and electronic properties of Cs structures on III-V (110) surfaces: From 1D and 2D insulators to 3D metals

LJ Whitman, JA Stroscio, RA Dragoset, RJ Celotta - Physical review letters, 1991 - APS
We report the structural and electronic properties of Cs adsorbed on room-temperature
GaAs and InSb (110) surfaces as observed with scanning tunneling microscopy. Cs initially …

Desorption of alkali atoms and ions from oxide surfaces: Relevance to origins of Na and K in atmospheres of Mercury and the Moon

TE Madey, BV Yakshinskiy, VN Ageev… - Journal of …, 1998 - Wiley Online Library
This paper begins with a brief survey of the literature dealing with the adsorption and
desorption of alkalis on oxide surfaces. Emphasis is on desorption phenomena: thermal …

Crystallographic study of interaction between adspecies on metal surfaces

H Over - progress in surface science, 1998 - Elsevier
The interaction among adsorbed atoms and molecules (adspecies) on metal surfaces plays
a decisive role in catalytic reactions. Such interaction may cause structural changes of the …

Coverage dependence of adsorption-site geometry in the Cs/Ru (0001) system: A low-energy electron-diffraction analysis

H Over, H Bludau, M Skottke-Klein, G Ertl, W Moritz… - Physical Review B, 1992 - APS
The ordered overlayer structures formed by Cs adsorbed on a Ru (0001) surface were
analyzed by use of low-energy electron diffraction (LEED). The phase diagram reflects the …

Photoemission Spectra and Electronic Properties of KxC60

GK Wertheim, JE Rowe, DNE Buchanan, EE Chaban… - Science, 1991 - science.org
Photoemission spectra of vacuum deposited layers of C60, before and after exposure to K
vapor, show that the K donates its conduction electron into the band derived from the lowest …

Photoemission study of K on graphite

P Bennich, C Puglia, PA Brühwiler, A Nilsson… - Physical Review B, 1999 - APS
The physical and electronic structure of the dispersed and (2× 2) phases of K/graphite have
been characterized by valence and core-level photoemission. Charge transfer from K to …